Perfluorophenyl derivatives of the elements : I. Tris(pentafluorophenyl)boron
作者： A.G. Massey , A.J. Park
DOI: 10.1016/S0022-328X(00)80518-5
关键词: Lewis acids and bases 、 Inorganic chemistry 、 Boron trichloride 、 Aqueous solution 、 Chemistry 、 Pyridine 、 Tris(pentafluorophenyl)borane 、 Triphenylphosphine 、 Boron 、 Acceptor 、 Polymer chemistry
摘要: Abstract The relatively stable white solid tris(pentafluorophenyl)boron has been prepared in high yield from boron trichloride and pentafluorophenyllithium using pentane as a solvent. It shows strong acceptor properties towards the Lewis bases: ammonia, trimethylamine, triphenylphosphine, pyridine. With excess of salt lithium tetrakis(pentafluorophenyl)borate is formed; water-soluble borate precipitates tetraethylammonium potassium derivatives concentrated aqueous solutions.
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