作者: Saim Özkar , Cornelius G. Kreiter
DOI: 10.1016/0022-328X(85)80292-8
关键词: Stereochemistry 、 Cycloaddition 、 Chromium 、 Medicinal chemistry 、 Hydrocarbon 、 Chemistry 、 Nuclear magnetic resonance spectroscopy 、 Coenzyme Q – cytochrome c reductase 、 Ligand
摘要: Abstract The photochemical reaction of tricarbonyl-η 6 -1,3,5-cycloheptatriene-chromium(0) (I) with tricyclo[6.3.0.0 2,7 ]undeca-3,5-diene (II) in n-pentane at 248 K yields the [4 + 6]-cycloadduct -pentacyclo[7.6.2.1 10,15 .0 2,8 3,7 ]octadeca-11,13,16-triene-chromium(0) (III). Detachment pentacyclic triene ligand from chromium can be achieved trimethylphosphite. constitutions complex III and hydrocarbon IV were determined by spectroscopic means.