Three-dimensional microporous graphene decorated with lithium.

作者: Marco Iacobucci , Iolanda Di Bernardo , Meganne Christian , Vittorio Morandi , Francesca Ripanti

DOI: 10.1088/1361-6528/AAD3F5

关键词: Photoemission spectroscopyMicroporous materialRaman spectroscopyGraphiteX-ray photoelectron spectroscopyChemical physicsMaterials scienceGrapheneAtomLithium

摘要: Three-dimensional (3D) graphene-based architectures can combine the two-dimensional properties of graphene with high surface-to-volume ratio required for a large variety technological applications. We present spectro-microscopy study stable microporous 3D few-layer structures very low density defects/edges and unsaturated bonds, as deduced by Raman core level photoemission spectroscopy. These qualities make these interconnected networks ideal candidates to accommodate lithium adatoms, Li per unit volume uptake C atom higher than value observed graphite, confirmed

参考文章(46)
Jusef Hassoun, Francesco Bonaccorso, Marco Agostini, Marco Angelucci, Maria Grazia Betti, Roberto Cingolani, Mauro Gemmi, Carlo Mariani, Stefania Panero, Vittorio Pellegrini, Bruno Scrosati, An Advanced Lithium-Ion Battery Based on a Graphene Anode and a Lithium Iron Phosphate Cathode Nano Letters. ,vol. 14, pp. 4901- 4906 ,(2014) , 10.1021/NL502429M
A. Capasso, A.E. Del Rio Castillo, H. Sun, A. Ansaldo, V. Pellegrini, F. Bonaccorso, Ink-jet printing of graphene for flexible electronics: An environmentally-friendly approach Solid State Communications. ,vol. 224, pp. 53- 63 ,(2015) , 10.1016/J.SSC.2015.08.011
V.A. Nalimova, D. Guérard, M. Lelaurain, O.V. Fateev, X-ray investigation of highly saturated Li-graphite intercalation compound Carbon. ,vol. 33, pp. 177- 181 ,(1995) , 10.1016/0008-6223(94)00123-H
Brian J. Landi, Matthew J. Ganter, Cory D. Cress, Roberta A. DiLeo, Ryne P. Raffaelle, Carbon nanotubes for lithium ion batteries Energy and Environmental Science. ,vol. 2, pp. 638- 654 ,(2009) , 10.1039/B904116H
Jun Liu, Charging graphene for energy Nature Nanotechnology. ,vol. 9, pp. 739- 741 ,(2014) , 10.1038/NNANO.2014.233
K. R. Kganyago, P. E. Ngoepe, Structural and electronic properties of lithium intercalated graphite LiC 6 Physical Review B. ,vol. 68, pp. 205111- ,(2003) , 10.1103/PHYSREVB.68.205111
Elisa Miniussi, M Pozzo, Alessandro Baraldi, ERIK Vesselli, RR Zhan, GIOVANNI Comelli, TO Menteş, MA Niño, A Locatelli, S Lizzit, D Alfè, None, Thermal Stability of Corrugated Epitaxial Graphene Grown on Re(0001) Physical Review Letters. ,vol. 106, pp. 216101- 216101 ,(2011) , 10.1103/PHYSREVLETT.106.216101
Lorenzo Massimi, Oualid Ourdjini, Leif Lafferentz, Matthias Koch, Leonhard Grill, Emanuele Cavaliere, Luca Gavioli, Claudia Cardoso, Deborah Prezzi, Elisa Molinari, Andrea Ferretti, Carlo Mariani, Maria Grazia Betti, Surface-Assisted Reactions toward Formation of Graphene Nanoribbons on Au(110) Surface Journal of Physical Chemistry C. ,vol. 119, pp. 2427- 2437 ,(2015) , 10.1021/JP509415R
Daniel R. Lenski, Michael S. Fuhrer, Raman and optical characterization of multilayer turbostratic graphene grown via chemical vapor deposition Journal of Applied Physics. ,vol. 110, pp. 013720- ,(2011) , 10.1063/1.3605545
Yu S Dedkov, M Fonin, Electronic and magnetic properties of the graphene ferromagnet interface New Journal of Physics. ,vol. 12, pp. 125004- ,(2010) , 10.1088/1367-2630/12/12/125004