作者: Gonzalo R. Malca Garcia , Lothar Hennig , Joachim Sieler , Rainer W. Bussmann
DOI: 10.1016/J.BJP.2015.02.007
关键词: Solid-state 、 Triterpene 、 Stereochemistry 、 Lupeol 、 Biology 、 Ketone 、 Balanophoraceae 、 Phytochemical 、 Corynaea crassa
摘要: A phytochemical investigation of methanol and n-hexane extracts tuber/roots Corynaea crassa Hook. f., Balanophoraceae, led to the isolation characterization β-sitosterol, lupenone, β-amyrone, lupeol, β-amyrine. Unusual complex 1:1 mixtures lupenone/β-amyrone lupeol/β-amyrine obtained from were identified by NMR HR-MS experiments. The structure mixture was confirmed X-ray analysis. These triterpene ketone derivatives, only distinguished either 5- or 6-membered E ring, co-crystallize in one common unit cell solid state.