Preparation and characterization of graphene reinforced PA6 fiber

作者: Lian Tang , Yiren Li , Ye Chen , Peng Ji , Chaosheng Wang

DOI: 10.1002/APP.45834

关键词: FiberComposite materialCrystallizationGrapheneOxideComposite numberIn situ polymerizationCaprolactamRelative viscosityMaterials scienceMaterials ChemistryGeneral chemistrySurfaces, Coatings and FilmsPolymers and Plastics

摘要: Here, we report the successful preparation of PA6/GO composite fibers through in situ polymerization and the melting spinning method. The results suggest that graphene has induced only minor changes on the relative viscosity yet exhibits significant effects on the crystallization characteristics. The SEM images of the fibers have shown several expended borders as a consequence of graphene addition. The maximum strength of the composite fibers (5.3 cN/dtex) has been reached 0.05 wt% graphene added to the system; the draw …

参考文章(56)
T.D. Fornes, D.R. Paul, Crystallization behavior of nylon 6 nanocomposites Polymer. ,vol. 44, pp. 3945- 3961 ,(2003) , 10.1016/S0032-3861(03)00344-6
Jiajie Liang, Yi Huang, Long Zhang, Yan Wang, Yanfeng Ma, Tianyin Guo, Yongsheng Chen, Molecular-Level Dispersion of Graphene into Poly(vinyl alcohol) and Effective Reinforcement of their Nanocomposites Advanced Functional Materials. ,vol. 19, pp. 2297- 2302 ,(2009) , 10.1002/ADFM.200801776
Tao Yang, Lin Ye, Ultraviolet Oxidative Stabilization Effect of the Rare Earth Compound on Polyamide Polymer-plastics Technology and Engineering. ,vol. 48, pp. 860- 865 ,(2009) , 10.1080/03602550902994920
Vitalijus Janickis, Skirma Žalenkienė, Formation and study of mixed copper sulfide-copper telluride layers on the surface of polyamide 6 Central European Journal of Chemistry. ,vol. 8, pp. 709- 724 ,(2010) , 10.2478/S11532-010-0060-9
Robert J. Young, Ian A. Kinloch, Lei Gong, Kostya S. Novoselov, The mechanics of graphene nanocomposites: A review Composites Science and Technology. ,vol. 72, pp. 1459- 1476 ,(2012) , 10.1016/J.COMPSCITECH.2012.05.005
Dorian Dixon, Patrick Lemonine, Jeremy Hamilton, Genady Lubarsky, Edward Archer, Graphene oxide–polyamide 6 nanocomposites produced via in situ polymerization: Journal of Thermoplastic Composite Materials. ,vol. 28, pp. 372- 389 ,(2015) , 10.1177/0892705713484749
Feifei Ma, Ningyi Yuan, Jianning Ding, The conductive network made up by the reduced graphene nanosheet/polyaniline/polyvinyl chloride Journal of Applied Polymer Science. ,vol. 128, pp. 3870- 3875 ,(2013) , 10.1002/APP.38624
C. Lechat, A. R. Bunsell, P. Davies, Tensile and creep behaviour of polyethylene terephthalate and polyethylene naphthalate fibres Journal of Materials Science. ,vol. 46, pp. 528- 533 ,(2011) , 10.1007/S10853-010-4999-X
Liping QIN, Shuquan LIANG, Yan TANG, Xiaoping TAN, Jiang ZHOU, Influence of PVP on Solvothermal Synthesized Fe 3 O 4 /Graphene Composites as Anodes for Lithium-ion Batteries Electrochemistry. ,vol. 83, pp. 619- 623 ,(2015) , 10.5796/ELECTROCHEMISTRY.83.619
Tong Hui Zhou, Wen Hong Ruan, Jing Lei Yang, Min Zhi Rong, Ming Qiu Zhang, Zhong Zhang, A novel route for improving creep resistance of polymers using nanoparticles Composites Science and Technology. ,vol. 67, pp. 2297- 2302 ,(2007) , 10.1016/J.COMPSCITECH.2007.01.015