17O NMR and Raman spectra of water with different calcium salts

作者: Ying Yan , Xiao-xia Ou , Hui-ping Zhang

DOI: 10.1016/J.MOLSTRUC.2014.05.075

关键词: Calcium saltsCalciumChemistryInorganic chemistryDistilled waterRaman spectroscopy

摘要: Abstract 17 O NMR and Raman spectra of water with different calcium salts have been measured. Different samples were prepared by adding nano-materials, gluconate, citrate chloride into distilled water. Both recorded. The effects temperature time on line-width analyzed as well. experimental results showed that these four almost the same those for when increased to 40 °C. decreased from 76.8 Hz 46.9 Hz 65.8 Hz after nano-materials added, respectively. Besides, 131.6 Hz was while 77.2 Hz gluconate added. other three nearly stable 30 °C 85 °C. kept steady all in 42 days.

参考文章(25)
Ruihua Li, Zhanpeng Jiang, Shaoqi Shi, Hongwei Yang, Raman spectra and 17O NMR study effects of CaCl2 and MgCl2 on water structure Journal of Molecular Structure. ,vol. 645, pp. 69- 75 ,(2003) , 10.1016/S0022-2860(02)00528-8
David M. Carey, Gerald M. Korenowski, Measurement of the Raman spectrum of liquid water Journal of Chemical Physics. ,vol. 108, pp. 2669- 2675 ,(1998) , 10.1063/1.475659
P. Terpstra, D. Combes, A. Zwick, Effect of salts on dynamics of water: A Raman spectroscopy study Journal of Chemical Physics. ,vol. 92, pp. 65- 70 ,(1990) , 10.1063/1.458418
F. N. Keutsch, R. J. Saykally, Water clusters: Untangling the mysteries of the liquid, one molecule at a time Proceedings of the National Academy of Sciences of the United States of America. ,vol. 98, pp. 10533- 10540 ,(2001) , 10.1073/PNAS.191266498
V. Arulmozhi, A. Srinivasa Rao, Proton Magnetic Resonance Relaxation Studies in Aqueous Solutions of Alkali Halides and Sugars Physics and Chemistry of Liquids. ,vol. 26, pp. 201- 207 ,(1993) , 10.1080/00319109308030663
G. E. Walrafen, Raman Spectral Studies of Water Structure Journal of Chemical Physics. ,vol. 40, pp. 3249- 3256 ,(1964) , 10.1063/1.1724992
J.A. Barker, R.O. Watts, Structure of water; A Monte Carlo calculation Chemical Physics Letters. ,vol. 3, pp. 144- 145 ,(1969) , 10.1016/0009-2614(69)80119-3
Ioannis P. Gerothanassis, Oxygen-17 NMR spectroscopy: basic principles and applications. Part II. Progress in Nuclear Magnetic Resonance Spectroscopy. ,vol. 57, pp. 95- 197 ,(2010) , 10.1016/J.PNMRS.2009.12.001
Zhorro S. Nickolov, Nikolay Goutev, Hiroatsu Matsuura, Hydrogen Bonding in Concentrated Aqueous Solutions of 1,2-Dimethoxyethane: Formation of Water Clusters Journal of Physical Chemistry A. ,vol. 105, pp. 10884- 10889 ,(2001) , 10.1021/JP011384Y