Heteroleptic metallacyclic potassium organodiamido zincate complex. Synthesis and structure of polymeric {[K(thf)][MeZn(ButNCHCHNBut)]}n
作者： Evelien Rijnberg , Jaap Boersma , Johann T. B. H. Jastrzebski , Miles T. Lakin , Anthony L. Spekt
DOI: 10.1039/C39950001839
关键词: Solid-state 、 Chemistry 、 Linear polymer 、 Radical 、 Zincate 、 Inorganic chemistry 、 Tetrahydrofuran 、 Potassium 、 Polymer chemistry 、 Dimer
摘要: The reaction of the C–C coupled dimer two neutral organozinc radicals, [MeZn(ButNCHCH(NBut)CH(NBut)CHNBut)ZnMe]1, with potassium in tetrahydrofuran affords metallacyclic neteroleptic organodiamido zincate K[MeZn(ButNCHCHNBut)]2 quantitatively, which exists solid state (X-ray crystallography) as a linear polymer formed by alternating cations and organodiamidozincate anions.
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