Crystalline mww-type titanosilicate , its preparation and use thereof for producing epoxides

作者: Katsuyuki Tsuji , Wataru Oguchi , Takashi Tatsumi , Peng Wu

DOI:

关键词: Materials scienceDouble bondPolymer chemistryRedoxPeroxideOrganic chemistryOxidizing agentCatalysisFunctional group

摘要: A crystalline titanosilicate catalyst which is usable as a in the oxidation reaction of compound having carbon-carbon double bond and at least one other functional group, process for producing catalyst, an oxidized by using catalyst. It has been found that structural code MWW effectively functions group wherein peroxide oxidizing agent, thereby to highly selectively provide intended compound.

参考文章(2)
Peng Wu, Takashi Tatsumi, Takayuki Komatsu, Tatsuaki Yashima, A Novel Titanosilicate with MWW Structure. I. Hydrothermal Synthesis, Elimination of Extraframework Titanium, and Characterizations Journal of Physical Chemistry B. ,vol. 105, pp. 2897- 2905 ,(2001) , 10.1021/JP002816S
Peng Wu, Takashi Tatsumi, Takayuki Komatsu, Tatsuaki Yashima, Hydrothermal Synthesis of a Novel Titanosilicate with MWW Topology Chemistry Letters. ,vol. 2000, pp. 774- 775 ,(2000) , 10.1246/CL.2000.774