Isosteric heat of hydrogen adsorption on MOFs: comparison between adsorption calorimetry, sorption isosteric method, and analytical models
作者： A. F. Kloutse , R. Zacharia , D. Cossement , R. Chahine , R. Balderas-Xicohténcatl
DOI: 10.1007/S00339-015-9484-6
关键词: Calorimetry 、 Chemistry 、 Thermal 、 Physical chemistry 、 Work (thermodynamics) 、 Thermal desorption spectroscopy 、 Adsorption 、 Microporous material 、 Thermodynamics 、 Hydrogen 、 Sorption
摘要: Isosteric heat of adsorption is an important parameter required to describe the thermal performance adsorptive storage systems. It most frequently calculated from isotherms measured over wide ranges pressure and temperature, using so-called isosteric method. Direct quantitative estimation heats on other hand possible coupled calorimetric–volumetric method, which involves simultaneous measurement adsorption. In this work, we compare hydrogen microporous materials by both methods. Furthermore, experimental data are compared with obtained modified Dubinin–Astakhov, Toth, Unilan analytical models establish reliability limitations simpler methods assumptions. To end, measure five prototypical metal–organic frameworks: MOF-5, Cu-BTC, Fe-BTC, MIL-53, MOF-177 For all MOFs, find a very good agreement between calorimetric throughout range loading studied. Models’ prediction deviates experiments depending MOF studied loading. Under low-loadings less than 5 mol kg−1, decreases in order Cu-BTC > MIL-53 MOF-5 Fe-BTC MOF-177. The coherent strength interaction revealed previous desorption spectroscopy measurements.
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Siyad Ubaid, Renju Zacharia, Jinsheng Xiao, Richard Chahine, Pierre Bénard, Pascal Tessier, Effect of flowthrough cooling heat removal on the performances of MOF-5 cryo-adsorptive hydrogen reservoir for bulk storage applications International Journal of Hydrogen Energy. ,vol. 40, pp. 9314- 9325 ,(2015) , 10.1016/J.IJHYDENE.2015.05.097
Jacob Bear, Yehuda Bachmat, Introduction to Modeling of Transport Phenomena in Porous Media ,(1991)
Jean Rouquerol, Françoise Rouquerol, Philip Llewellyn, Guillaume Maurin, Kenneth Sing, Adsorption by Powders and Porous Solids: Principles, Methodology and Applications ,(1998)
W Zimmermann, J.U Keller, A new calorimeter for simultaneous measurement of isotherms and heats of adsorption Thermochimica Acta. ,vol. 405, pp. 31- 41 ,(2003) , 10.1016/S0040-6031(03)00133-3
E. Poirier, R. Chahine, P. Bénard, L. Lafi, G. Dorval-Douville, P. A. Chandonia, Hydrogen Adsorption Measurements and Modeling on Metal-Organic Frameworks and Single-Walled Carbon Nanotubes Langmuir. ,vol. 22, pp. 8784- 8789 ,(2006) , 10.1021/LA061149C
Maurice Schlichtenmayer, Michael Hirscher, Nanosponges for hydrogen storage Journal of Materials Chemistry. ,vol. 22, pp. 10134- 10143 ,(2012) , 10.1039/C2JM15890F
K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems Chemical Engineering Journal. ,vol. 156, pp. 2- 10 ,(2010) , 10.1016/J.CEJ.2009.09.013
Ivana Krkljus, Michael Hirscher, Characterization of hydrogen/deuterium adsorption sites in nanoporous Cu―BTC by low-temperature thermal-desorption mass spectroscopy Microporous and Mesoporous Materials. ,vol. 142, pp. 725- 729 ,(2011) , 10.1016/J.MICROMESO.2011.01.023
Steven S. Kaye, Anne Dailly, Omar M. Yaghi, Jeffrey R. Long, Impact of preparation and handling on the hydrogen storage properties of Zn4O(1,4-benzenedicarboxylate)3 (MOF-5). Journal of the American Chemical Society. ,vol. 129, pp. 14176- 14177 ,(2007) , 10.1021/JA076877G
L E Vilchiz-Bravo, A Pacheco-Vega, B E Handy, Heat-flow and temperature control in Tian?Calvet microcalorimeters: toward higher detection limits Measurement Science and Technology. ,vol. 21, pp. 115103- ,(2010) , 10.1088/0957-0233/21/11/115103