Reactive and Organosoluble SnO2 Nanoparticles by a Surfactant‐Free Non‐Hydrolytic Sol–Gel Route
作者： Abdelhay Aboulaich , Bruno Boury , P. Hubert Mutin
关键词: Chemistry 、 Nanoparticle 、 Diisopropyl ether 、 Nanostructure 、 Sol-gel 、 Monolayer 、 Inorganic chemistry 、 Pulmonary surfactant 、 Polymer chemistry 、 Wafer 、 Nanocrystal
摘要: Reactive SnO2 nanoparticles have been successfully prepared by a simple non-hydrolytic sol–gel synthesis in CH2Cl2 at 110 °C using SnCl4 as precursor and diisopropyl ether (iPr2O) an oxygen donor. The nanocrystals, with diameter of about 4 nm, formed stable sols organic aprotic solvents the absence any surfactant or coordinating agent. lack aggregation has attributed to presence Cl OiPr surface groups instead OH groups. These render reactive towards hydroxylated surfaces, shown their reaction oxidized silicon wafer; bind uniformly across wafer form monolayer.
sci-hub.se 参考文章(45)
Didier Robert, Photosensitization of TiO2 by MxOy and MxSy nanoparticles for heterogeneous photocatalysis applications Catalysis Today. ,vol. 122, pp. 20- 26 ,(2007) , 10.1016/J.CATTOD.2007.01.060
Damien P. Debecker, Karim Bouchmella, Claude Poleunis, Pierre Eloy, Patrick Bertrand, Eric M. Gaigneaux, P. Hubert Mutin, Design of SiO2−Al2O3−MoO3 Metathesis Catalysts by Nonhydrolytic Sol−Gel Chemistry of Materials. ,vol. 21, pp. 2817- 2824 ,(2009) , 10.1021/CM900490T
Tiago G Conti, Adenilson J Chiquito, Rafael O Da Silva, Elson Longo, Edson R Leite, None, Electrical Properties of Highly Conducting SnO2:Sb Nanocrystals Synthesized using a Nonaqueous Sol-Gel Method Journal of the American Ceramic Society. ,vol. 93, pp. 3862- 3866 ,(2010) , 10.1111/J.1551-2916.2010.03979.X
T Sahm, L Mädler, A Gurlo, N Barsan, Sotiris E Pratsinis, U Weimar, Flame spray synthesis of tin dioxide nanoparticles for gas sensing Sensors and Actuators B-chemical. ,vol. 98, pp. 148- 153 ,(2004) , 10.1016/J.SNB.2003.10.003
Timothy J. Trentler, Tiffany E. Denler, Jane F. Bertone, Aarti Agrawal, Vicki L. Colvin, Synthesis of TiO2 Nanocrystals by Nonhydrolytic Solution-Based Reactions Journal of the American Chemical Society. ,vol. 121, pp. 1613- 1614 ,(1999) , 10.1021/JA983361B
Azam Anaraki Firooz, Ali Reza Mahjoub, Abbas Ali Khodadadi, Preparation of SnO2 nanoparticles and nanorods by using a hydrothermal method at low temperature Materials Letters. ,vol. 62, pp. 1789- 1792 ,(2008) , 10.1016/J.MATLET.2007.10.004
Laetitia Renard, Hicham Elhamzaoui, Bernard Jousseaume, Thierry Toupance, Guillaume Laurent, François Ribot, Hassan Saadaoui, Joachim Brötz, Hartmut Fuess, Ralf Riedel, Aleksander Gurlo, Low-temperature H2 sensing in self-assembled organotin thin films Chemical Communications. ,vol. 47, pp. 1464- 1466 ,(2011) , 10.1039/C0CC04188B
G-J Li, X-H Zhang, S Kawi, Relationships between sensitivity, catalytic activity, and surface areas of SnO2 gas sensors Sensors and Actuators B-chemical. ,vol. 60, pp. 64- 70 ,(1999) , 10.1016/S0925-4005(99)00245-2
Sophie de Monredon, Antoine Cellot, Fran??ois Ribot, Cl??ment Sanchez, Lidia Armelao, Lethicia Gueneau, Laurent Delattre, Synthesis and characterization of crystalline tin oxide nanoparticles Journal of Materials Chemistry. ,vol. 12, pp. 2396- 2400 ,(2002) , 10.1039/B203049G
Àngel Diéguez Barrientos, Albert Romano Rodríguez, Anna Maria Vilà i Arbonès, Joan Ramon Morante i Lleonart, The complete Raman spectrum of nanometric SnO2 particles Journal of Applied Physics. ,vol. 90, pp. 1550- 1557 ,(2001) , 10.1063/1.1385573