Process for producing a silicone oligomer solution and organopolysiloxane film formed from the solution

作者: Zuyi Nihon Yamamura Glass Co. Ltd. Zhang

DOI:

关键词: SiliconeAlkylPolymer chemistryBase (chemistry)Phenyl groupOligomerStructural unitGroup (periodic table)Organic chemistryMaterials scienceCarbon

摘要: A process for producing a solution of silicone oligomer which comprises adding to an alkoxysilane, as self-catalyst, comprising silicon compound is soluble in hydrophilic solvents and has average structural unit represented by R1 nSiOx/2(OH)y(OR2)z, wherein represents alkyl group having 1 3 carbon atoms, vinyl or phenyl group, plurality may represent same different groups, R2 groups n, x, y z numbers satisfying relations: 0≦n 0, z≧0 y+z=4-n-x, hydrolyzing polycondensing the alkoxysilane; film organopolysiloxane formed from oligomer. In accordance with process, exhibits excellent storage stability high concentrations contains small no amounts acid base components produced alkoxysilane above physical properties.

参考文章(14)
Claus Lindzus, Bruno Luthringshauser, Impregnating agent for materials containing cellulose ,(1980)
Seiichiro c, Haruo c, Hanako c, Hozumi c, o Kurosaki Dev. Ctr Takazawa, o Mitsubishi Chem. Corp. Katsumata, o Kurosaki Dev. Ctr Endo, o Kurosaki Dev. Ctr Kato, o Kurosaki Dev. Ctr Sawai, o Kurosaki Dev. Ctr Tanaka, Akihiro c, Takeshi c, Polyalkoxysiloxane and process for its production ,(1996)
Robert Lehnert, Uwe Scheim, Uwe Bankwitz, Peter Jenkner, Alkoxy-crosslinking rtv1 silicone rubber mixtures ,(1998)
Franz-Heinrich Kreuzer, Gisela Glauberman, Erhard Bosch, Silanes and compositions prepared therefrom ,(1982)
Haruo Katsumata, Kenji Oba, Seiichirou Tanaka, Takeshi Sawai, Hanako Kato, Hozumi Endo, Siloxane compounds, process for preparing the same, and liquid composition containing the same ,(1997)
Lindzus Claus, Luthringshauser Bruno, IMPREGNATION AGENT FOR CELLULOSIC MATERIALS ,(1983)
Minoru Tamura, 稔 田村, Production of siloxane polymer ,(1997)
Kinji Yamada, Yoshinori Yoshida, Masaki Nagata, Hideyuki Hanaoka, Coating composition and production thereof ,(1986)
Haruo Katsumata, Takeshi Sawai, 功三郎 松村, Kouzaburou Matsumura, 毅 沢井, 晴雄 勝俣, Minoru Yasueda, 稔 安枝, Silane oligomer composition ,(1997)
Sawai Takeshi, Adachi Koichi, Tanaka Seiichiro, Matsuzoe Nobuyuki, POLYSILOXANE OLIGOMER AND ITS PRODUCTION ,(1996)