Isotopic composition analyzer

作者: Hanns-Ludwig Schmidt , Ramiro Medina

DOI:

关键词: CarbonCarbon monoxideNitrogenAnalytical chemistryOxygenMass spectrometryCatalysisSpectrometerHydrogenChemistry

摘要: An on-line mass spectrometric method and apparatus for the determination of isotopic composition at least oxygen, hydrogen nitrogen in a compound or mixture compounds. A contained syringe 6 is injected through injector 7 on chromatographic column 1. Compounds eluting from 1 pass into catalytic reactor 14 containing carbon are decomposed to produce monoxide, molecular nitrogen, hydrogen. These gases analyzed by an isotope-ratio spectrometer 4 so that comprised original can be determined. second 24 may provided separate monoxide before they passed 4, thereby allowing low resolution used analysis both m/e 28 daltons.

参考文章(5)
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Jeffrey. Santrock, J. M. Hayes, Adaptation of the Unterzaucher procedure for determination of oxygen-18 in organic substances Analytical Chemistry. ,vol. 59, pp. 119- 127 ,(1987) , 10.1021/AC00128A025