Spin dynamics in conducting polymers studied by μSR

作者: F.L. Pratt , S.J. Blundell , P.A. Pattenden , W. Hayes , K.H. Chow

DOI: 10.1023/A:1012652816077

关键词: Spin diffusionSpin polarizationPolyanilineCondensed matter physicsMuon spin spectroscopySpin waveZero field splittingRelaxation (NMR)ChemistrySpin-½

摘要: We report studies of spin dynamics in the conducting polymers polyaniline and polypyrrole using both μ+SR μ-SR techniques. These measurements reveal characteristic field dependences cutoff frequencies for muon relaxation which can be related to diffusion process. Clear evidence is seen increased localisation at low temperatures where a crossover occurs from two or three dimensional one regime.

参考文章(6)
K. Nagamine, K. Ishida, T. Matsuzaki, K. Nishiyama, Y. Kuno, T. Yamazaki, H. Shirakawa, Solitons in Polyacetylene Produced and Probed by Positive Muons Physical Review Letters. ,vol. 53, pp. 1763- 1766 ,(1984) , 10.1103/PHYSREVLETT.53.1763
M. A. Butler, L. R. Walker, Z. G. Soos, Dimensionality of spin fluctuations in highly anisotropic TCNQ salts The Journal of Chemical Physics. ,vol. 64, pp. 3592- 3601 ,(1976) , 10.1063/1.432709
F.L. Pratt, W. Hayes, G.R. Mitchell, B. Rossi, M.S. Kiani, B.D. Malhotra, S.S. Pandey, A. Milton, A.P. Monkman, Muon studies of conducting polymers Synthetic Metals. ,vol. 55, pp. 677- 684 ,(1993) , 10.1016/0379-6779(93)91011-P
Kenji Mizoguchi, Kiyoshi Kume, Metallic temperature dependence in the conducting polymer, polyaniline : spin dynamics study by ESR Solid State Communications. ,vol. 89, pp. 971- 975 ,(1994) , 10.1016/0038-1098(94)90497-9
T. Ishiguro, H. Kaneko, Y. Nogami, H. Ishimoto, H. Nishiyama, J. Tsukamoto, A. Takahashi, M. Yamaura, T. Hagiwara, K. Sato, Logarithmic temperature dependence of resistivity in heavily doped conducting polymers at low temperature Physical Review Letters. ,vol. 69, pp. 660- 663 ,(1992) , 10.1103/PHYSREVLETT.69.660
F. Devreux, J.-P. Boucher, M. Nechtschein, Temps de relaxation nucléaire T1D et T1ρ en présence de mouvement de spins électroniques Journal De Physique. ,vol. 35, pp. 271- 285 ,(1974) , 10.1051/JPHYS:01974003503027100