Four luminescent metal-organic chain compounds based on semi-rigid N-donor ligands and 3-hydroxy-2-naphthoic acid for recognition of Fe3+ and Cr2O72− ions
作者： Xiang Wang , Hanyu Xiao , Mingze Zhang , Hongyan Lin , Guocheng Liu
DOI: 10.1016/J.POLY.2020.114383
关键词: Selectivity 、 Polymer chemistry 、 Linear molecular geometry 、 Benzene 、 Covalent bond 、 Biphenyl 、 Luminescence 、 Metal 、 Chemistry 、 Ion
摘要: Abstract Four luminescent metal-organic complexes based on semi-rigid N-donor ligands and 3-hydroxy-2-naphthoic acid (3-HNA), [Zn(bimb)(3-HNA)2] (1), [Zn(bbimb)(3-HNA)2]·3H2O (2), [Zn(bimbp)(3-HNA)2] (3), [Cd(bimbp)(3-HNA)2] (4) [bimb = 1,4-bis(1-imidazol-yl-methyl)benzene, bimbp = 4,4′-bis(1H-imidazol-1-yl-methyl)biphenyl, bbimb = 1,4-bis(1-benzimidazolyl-yl-methyl)benzene], have been synthesized solvothermally. The 1D chain structures of 1–4 exhibit the Z-type or linear geometry configurations, where combination transition metal ions is regarded as backbones, 3-HNA are dangled covalently both sides such backbone. investigation luminescence properties indicates that detection capabilities against Fe3+ Cr2O72− in DMF with excellent selectivity sensitivity.
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