Versatile postmodification of linear poly-p-phenylene to prepare microporous polymeric networks using the double aromatic nucleophilic substitution reaction
作者： Liming Tao , Junping Ju , Fang Niu , Tingmei Wang , Qihua Wang
DOI: 10.1016/J.POLYMER.2013.07.075
关键词: Polymerization 、 Polymer chemistry 、 Pore size 、 Reagent 、 Adsorption 、 Microporous material 、 Nucleophilic substitution 、 Acid catalyzed 、 Poly(p-phenylene) 、 Materials science
摘要: Abstract Microporous, hypercrosslinked poly-p-phenylenes with surface area of up to 1735 m2 g−1 have been prepared by combination super acid catalyzed polymerization and the double aromatic nucleophilic substitution reaction. The pore size can be controlled varying amount crosslinking reagents, which tuned degree effectively. capacity adsorption CO2 MPNs largely depends on their specific areas.
irgrid.ac.cn参考文章(44)
Functional Metal-Organic Frameworks: Gas Storage, Separation and Catalysis fmfg. ,vol. 293, ,(2010) , 10.1007/978-3-642-14613-8
M. Carmen G. Hernandez, Mikhail G. Zolotukhin, Serguei Fomine, Gerardo Cedillo, Salvador L. Morales, Nils Fröhlich, Eduard Preis, Ullrich Scherf, Manuel Salmón, Maria Isabel Chávez, Jorge Cárdenas, Alberto Ruiz-Trevino, Novel, Metal-Free, Superacid-Catalyzed “Click” Reactions of Isatins with Linear, Nonactivated, Multiring Aromatic Hydrocarbons Macromolecules. ,vol. 43, pp. 6968- 6979 ,(2010) , 10.1021/MA101048Z
Jun-Young Lee, Colin D. Wood, Darren Bradshaw, Matthew J. Rosseinsky, Andrew I. Cooper, Hydrogen adsorption in microporous hypercrosslinked polymers Chemical Communications. pp. 2670- 2672 ,(2006) , 10.1039/B604625H
Yi Ouyang, Huimin Shi, Ruowen Fu, Dingcai Wu, Highly monodisperse microporous polymeric and carbonaceous nanospheres with multifunctional properties. Scientific Reports. ,vol. 3, pp. 1430- 1430 ,(2013) , 10.1038/SREP01430
Rhys Short, Mariolino Carta, C. Grazia Bezzu, Detlev Fritsch, Benson M. Kariuki, Neil B. McKeown, Hexaphenylbenzene-based polymers of intrinsic microporosity Chemical Communications. ,vol. 47, pp. 6822- 6824 ,(2011) , 10.1039/C1CC11717C
Victor M. Velasco, Mikhail G. Zolotukhin, Maria Teresa Guzmán-Gutiérrez, Salvador Lopez Morales, Serguei Fomine, Maria P. Carreón-Castro, Manuel Salmón, Ullrich Scherf, Novel Aromatic Polymers with Pentafluorophenyl Pendent Groups Macromolecules. ,vol. 41, pp. 8504- 8512 ,(2008) , 10.1021/MA8016162
Yugen Zhang, Siti Nurhanna Riduan, Functional porous organic polymers for heterogeneous catalysis Chem. Soc. Rev.. ,vol. 41, pp. 2083- 2094 ,(2012) , 10.1039/C1CS15227K
M.P Tsyurupa, V.A Davankov, Hypercrosslinked polymers: basic principle of preparing the new class of polymeric materials Reactive and Functional Polymers. ,vol. 53, pp. 193- 203 ,(2002) , 10.1016/S1381-5148(02)00173-6
Buyi Li, Zhenhong Guan, Wei Wang, Xinjia Yang, Jianglin Hu, Bien Tan, Tao Li, Highly Dispersed Pd Catalyst Locked in Knitting Aryl Network Polymers for Suzuki–Miyaura Coupling Reactions of Aryl Chlorides in Aqueous Media Advanced Materials. ,vol. 24, pp. 3390- 3395 ,(2012) , 10.1002/ADMA.201200804
Yali Luo, Buyi Li, Wei Wang, Kangbing Wu, Bien Tan, Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO2 Capturing Materials Advanced Materials. ,vol. 24, pp. 5703- 5707 ,(2012) , 10.1002/ADMA.201202447