Experimental Determination of the Oscillator Strength of the Violet System of OH
作者： R. G. Bennett , F. W. Dalby
DOI: 10.1063/1.1725326
关键词: Molecule 、 Methanol 、 Extrapolation 、 Moment (physics) 、 Quenching (fluorescence) 、 Atomic physics 、 Radiative transfer 、 Molecular electronic transition 、 Oscillator strength 、 Chemistry 、 Physical and Theoretical Chemistry 、 General Physics and Astronomy
摘要: The radiative lifetime of the A 2Σ→X 2Π transition OH has been measured. apparent is dependent upon pressure parent molecule from which OH* produced by electron bombardment. Extrapolation to zero yields a spontaneous probability 0.99×106 sec—1 corresponding an oscillator strength f= (7.25±0.5) 10—4. This value assumes that electronic moment constant over (0, 0) vibrational transition. Utilizing Learner's values rotation—vibration interaction f for rotationless and band (8.0±0.8) collisional quenching cross sections between water or methanol are 70×10—16 cm2 110×10—16 cm2, respectively.
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sci-hub.se 参考文章(14)
R. G. Bennett, E. W. Dalby, Experimental Oscillator Strength of the Comet‐Tail System of CO+ Journal of Chemical Physics. ,vol. 32, pp. 1111- 1113 ,(1960) , 10.1063/1.1730857
D. M. Golden, F. P. Del Greco, F. Kaufman, Experimental Oscillator Strength of OH,2Σ+→2Π, by a Chemical Method The Journal of Chemical Physics. ,vol. 39, pp. 3034- 3041 ,(1963) , 10.1063/1.1734139
R. H. Lyddane, F. T. Rogers, F. E. Roach, The Abundances of Molecules in the Solar Reversing Layer Physical Review. ,vol. 60, pp. 281- 282 ,(1941) , 10.1103/PHYSREV.60.281
R W Nicholls, W R Jarmain, r-Centroids: Average Internuclear Separations Associated with Molecular Bands Proceedings of the Physical Society. Section A. ,vol. 69, pp. 253- 264 ,(1956) , 10.1088/0370-1298/69/3/308
R. J. Dwyer, O. Oldenberg, The Dissociation of H2O into H+OH The Journal of Chemical Physics. ,vol. 12, pp. 351- 361 ,(1944) , 10.1063/1.1723957
Tucker Carrington, Line Shape and f Value in the OH 2Σ+ — 2Π Transition The Journal of Chemical Physics. ,vol. 31, pp. 1243- 1252 ,(1959) , 10.1063/1.1730577
Frank P. Del Greco, Frederick Kaufman, Lifetime and reactions of OH radicals in discharge-flow systems Discussions of the Faraday Society. ,vol. 33, pp. 128- 138 ,(1962) , 10.1039/DF9623300128
M. Lapp, Shock-tube measurements of the f-number for the (0, 0)-band of the OH 2∑ → 2Π transitions Journal of Quantitative Spectroscopy and Radiative Transfer. ,vol. 1, pp. 30- 45 ,(1961) , 10.1016/0022-4073(61)90009-7
P. J. Dyne, Uncertainties in the Measurement of the Oscillator Strength of the Ultraviolet Bands of OH Journal of Chemical Physics. ,vol. 28, pp. 999- 1000 ,(1958) , 10.1063/1.1744333
R. G. Bennett, F. W. Dalby, Experimental Oscillator Strength of the Violet System of CN The Journal of Chemical Physics. ,vol. 36, pp. 399- 400 ,(1962) , 10.1063/1.1732517