Avoidance of 2 Al atoms in a 5-ring a new rule complementing the Loewenstein's rule

作者: Masanao Kato , Hidenori Araki , Keiji Itabashi

DOI: 10.1016/S0167-2991(06)81182-1

关键词: Ring (chemistry)Distribution (number theory)Molecular physicsPhysicsLimit (mathematics)

摘要: A new rule is proposed which restricts the distribution of Al atoms in zeolitic frameworks complementing Loewenstein's rule. The shows that any 5-ring a siliceous framework can not contain two atoms, and applied to determine lowest limit Si/Al ratio these zeolites.

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Keiichi Shiokawa, Masatoki Ito, Keiji Itabashi, Crystal structure of synthetic mordenites Zeolites. ,vol. 9, pp. 170- 176 ,(1989) , 10.1016/0144-2449(89)90021-3