Steady-state modeling of slurry and bulk propylene polymerizations

作者: A.G. Mattos Neto , J.C. Pinto

DOI: 10.1016/S0009-2509(01)00076-8

关键词: Flexural modulusPolymerizationMolar mass distributionBulk polymerizationParticle-size distributionTacticityThermodynamicsPolymerMaterials scienceSlurryPolymer chemistryIndustrial and Manufacturing EngineeringApplied mathematicsGeneral chemistryGeneral Chemical Engineering

摘要: … with actual operation data collected at two different plant sites to validate the model, for both propylene homopolymerizations and high impact ethylene/propylene copolymerizations. …

参考文章(47)
E. Shamshoum, J. Schardl, Impact of Metallocene Based Polypropylene on Existing Polypropylene Technologies and Markets Metallocene Catalyzed Polymers#R##N#Materials, Properties, Processing & Markets. pp. 359- 368 ,(1998) , 10.1016/B978-188420759-4.50047-4
Monica A. Ferrero, Mario G. Chiovetta, Catalyst fragmentation during propylene polymerization: Part II. Microparticle diffusion and reaction effects Polymer Engineering and Science. ,vol. 27, pp. 1448- 1460 ,(1987) , 10.1002/PEN.760271904
L.M. Rincon-Rubio, C-E. Wilen, L-E. Lindfors, A kinetic model for the polymerization of propylene over a Ziegler-Natta catalyst European Polymer Journal. ,vol. 26, pp. 171- 176 ,(1990) , 10.1016/0014-3057(90)90183-5
Kyu-Yong Choi, W. Harmon Ray, The dynamic behaviour of fluidized bed reactors for solid catalysed gas phase olefin polymerization Chemical Engineering Science. ,vol. 40, pp. 2261- 2279 ,(1985) , 10.1016/0009-2509(85)85128-9
Priyabrata Sarkar, Santosh K. Gupta, Dynamic simulation of propylene polymerization in continuous flow stirred tank reactors Polymer Engineering and Science. ,vol. 33, pp. 368- 374 ,(1993) , 10.1002/PEN.760330610
Monica A. Ferrero, Mario G. Chiovetta, Effects of catalyst fragmentation during propylene polymerization. IV: Comparison between gas phase and bulk polymerization processes Polymer Engineering and Science. ,vol. 31, pp. 904- 911 ,(1991) , 10.1002/PEN.760311209
R. A. Hutchinson, C. M. Chen, W. H. Ray, Polymerization of olefins through heterogeneous catalysis X: Modeling of particle growth and morphology Journal of Applied Polymer Science. ,vol. 44, pp. 1389- 1414 ,(1992) , 10.1002/APP.1992.070440811
A. Pabedinskas, W. R. Cluett, S. T. Balke, Modeling of polypropylene degradation during reactive extrusion with implications for process control Polymer Engineering and Science. ,vol. 34, pp. 598- 612 ,(1994) , 10.1002/PEN.760340708