Application of γ‐Valerolactone as an Alternative Biomass‐Based Medium for Aminocarbonylation Reactions
作者： Diána Marosvölgyi-Haskó , Blanka Lengyel , József M. Tukacs , László Kollár , László T. Mika
关键词: Homogeneous catalysis 、 Valerolactone 、 Vapor pressure 、 Organic chemistry 、 Bar (unit) 、 Carbon monoxide 、 Carbonylation 、 Inorganic chemistry 、 Iodobenzene 、 gamma-Valerolactone 、 Chemistry
摘要: -Valerolactone was proposed as a renewable, non-toxic reaction medium having negligible vapor pressure for homogeneous Pd-catalyzed aminocarbonylation reactions. Iodobenzene model substrate and its 4-substituted derivatives were converted to the corresponding 2-ketocarboxamides with high conversion chemoselectivities in -valerolactone. The effect of carbon monoxide temperature on selectivities studied range 1-50 bar 25-100 °C, respectively. highest selectivitiy achieved at 25 50 °C iodobenzene GVL 24 h.
sci-hub.se 参考文章(63)
Tianbin Wu, Buxing Han, Supercritical Carbon Dioxide (CO2) as Green Solvent Innovations in Green Chemistry and Green Engineering. pp. 297- 326 ,(2013) , 10.1007/978-1-4614-5817-3_10
Viktória Fábos, Matthew Y. Lui, Yiu Fung Mui, Yuet Yan Wong, László T. Mika, Long Qi, Edit Cséfalvay, Viktória Kovács, Tibor Szűcs, István T. Horváth, Use of Gamma-Valerolactone as an Illuminating Liquid and Lighter Fluid ACS Sustainable Chemistry & Engineering. ,vol. 3, pp. 1899- 1904 ,(2015) , 10.1021/ACSSUSCHEMENG.5B00465
József M. Tukacs, Bálint Fridrich, Gábor Dibó, Edit Székely, László T. Mika, Direct asymmetric reduction of levulinic acid to gamma-valerolactone: synthesis of a chiral platform molecule Green Chemistry. ,vol. 17, pp. 5189- 5195 ,(2015) , 10.1039/C5GC01099C
Péter Pongrácz, László Kollár, László T. Mika, A step towards hydroformylation under sustainable conditions: platinum-catalysed enantioselective hydroformylation of styrene in gamma-valerolactone Green Chemistry. ,vol. 18, pp. 842- 847 ,(2016) , 10.1039/C5GC01778E
F. OZAWA, T. SUGIMOTO, T. YAMAMOTO, A. YAMAMOTO, Preparation of trans-Pd(COCOR)Cl(PMePh2)2 complexes (R = Ph and Me) and their reactivities relative to double carbonylation promoted by palladium Organometallics. ,vol. 3, pp. 692- 697 ,(1984) , 10.1002/CHIN.198433277
Xiao-Feng Wu, Helfried Neumann, Matthias Beller, Synthesis of Heterocycles via Palladium-Catalyzed Carbonylations Chemical Reviews. ,vol. 113, pp. 1- 35 ,(2013) , 10.1021/CR300100S
Viktória Fábos, Gabriella Koczó, Hasan Mehdi, László Boda, István T. Horváth, Bio-oxygenates and the peroxide number: a safety issue alert Energy and Environmental Science. ,vol. 2, pp. 767- 769 ,(2009) , 10.1039/B900229B
J. K. Nickerson, K. A. Kobe, John J. McKetta, THE THERMODYNAMIC PROPERTIES OF THE METHYL KETONE SERIES The Journal of Physical Chemistry. ,vol. 65, pp. 1037- 1043 ,(1961) , 10.1021/J100824A038
William E. Putnam, Douglas Marvin McEachern, John E. Kilpatrick, Entropy and Related Thermodynamic Properties of Acetonitrile (Methyl Cyanide) The Journal of Chemical Physics. ,vol. 42, pp. 749- 755 ,(1965) , 10.1063/1.1696002
Santiago Aparicio, Rafael Alcalde, The green solvent ethyl lactate: an experimental and theoretical characterization Green Chemistry. ,vol. 11, pp. 65- 78 ,(2009) , 10.1039/B811909K