Dual functional MoS2/graphene interlayer as an efficient polysulfide barrier for advanced lithium-sulfur batteries

作者: Pengqian Guo , Dequan Liu , Zhengjiao Liu , Xiaonan Shang , Qiming Liu

DOI: 10.1016/J.ELECTACTA.2017.10.003

关键词: Chemical engineeringGrapheneMaterials scienceElectrochemistryCathodeCurrent collectorPolysulfideComposite numberLithiumSulfur utilizationNanotechnology

摘要: Abstract A dual functional interlayer consisted of composited two-dimensional MoS 2 and graphene has been developed as an efficient polysulfide barrier for lithium-sulfur batteries (LSBs). With such a configuration, LSBs show superior rate capacity improved cycling capacity. The excellent electrochemical performance can be attributed to the strong bonding interactions between /graphene formed lithium polysulfides (LiPSs) well good electrical conductivity composite. physically block LiPSs by nanosheets chemically suppress dissolution polar nanoflowers. Such further provides contact with surface sulfur cathode, acts upper current collector greatly improves utilization capability LSBs.

参考文章(37)
Guangmin Zhou, Eunsu Paek, Gyeong S. Hwang, Arumugam Manthiram, Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge Nature Communications. ,vol. 6, pp. 7760- 7760 ,(2015) , 10.1038/NCOMMS8760
Liyuan Chai, Jiexi Wang, Haiying Wang, Liyuan Zhang, Wanting Yu, Liqiang Mai, Porous carbonized graphene-embedded fungus film as an interlayer for superior Li–S batteries Nano Energy. ,vol. 17, pp. 224- 232 ,(2015) , 10.1016/J.NANOEN.2015.09.001
Jian-Gan Wang, Keyu Xie, Bingqing Wei, Advanced engineering of nanostructured carbons for lithium–sulfur batteries Nano Energy. ,vol. 15, pp. 413- 444 ,(2015) , 10.1016/J.NANOEN.2015.05.006
Xuefeng Wang, Zhaoxiang Wang, Liquan Chen, Reduced graphene oxide film as a shuttle-inhibiting interlayer in a lithium–sulfur battery Journal of Power Sources. ,vol. 242, pp. 65- 69 ,(2013) , 10.1016/J.JPOWSOUR.2013.05.063
Arumugam Manthiram, Yongzhu Fu, Yu-Sheng Su, Challenges and prospects of lithium-sulfur batteries. Accounts of Chemical Research. ,vol. 46, pp. 1125- 1134 ,(2013) , 10.1021/AR300179V
Zhian Zhang, Qiang Li, Kai Zhang, Yanqing Lai, Jie Li, Micro-nano structure composite cathode material with high sulfur loading for advanced lithium–sulfur batteries Electrochimica Acta. ,vol. 152, pp. 53- 60 ,(2015) , 10.1016/J.ELECTACTA.2014.11.099
Yuan Yang, Guangyuan Zheng, Yi Cui, None, Nanostructured sulfur cathodes Chemical Society Reviews. ,vol. 42, pp. 3018- 3032 ,(2013) , 10.1039/C2CS35256G
Guoqiang Ma, Zhaoyin Wen, Meifen Wu, Chen Shen, Qingsong Wang, Jun Jin, Xiangwei Wu, A lithium anode protection guided highly-stable lithium-sulfur battery Chemical Communications. ,vol. 50, pp. 14209- 14212 ,(2014) , 10.1039/C4CC05535G
Xiulei Ji, Kyu Tae Lee, Linda F. Nazar, A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries Nature Materials. ,vol. 8, pp. 500- 506 ,(2009) , 10.1038/NMAT2460
M. Armand, J.-M. Tarascon, Building better batteries Nature. ,vol. 451, pp. 652- 657 ,(2008) , 10.1038/451652A