Chemistry of compounds containing metal-to-metal triple bonds between molybdenum and tungsten
作者： Malcolm H. Chisholm , F. Albert Cotton
DOI: 10.1021/AR50129A006
关键词: Alkyl 、 Chemical bond 、 Triple bond 、 Tungsten 、 Chemistry 、 Tungsten Compounds 、 Inorganic chemistry 、 Molecule 、 Polymer chemistry 、 Halide 、 Molybdenum
摘要: Abstract : The preparation, properties, structures, dynamical solution behaviors and reactivities towards small unsaturated molecules (CO2, acetylenes, CO, etc.) are described for a series of molybdenum tungsten compounds general formula M2X6 or M2X6-nY, where X Y=R (alkyl), NR2, or, O2CNR2, O2COR halide, Cp2M2(CO)4, all which contain triple bonds between the metal atoms (M=Mo W). (Author)
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