Self‐organizing systems based on amphiphilic cyclodextrin diesters

作者: Ping Zhang , H�l�ne Parrot-lopez , Pierre Tchoreloff , Adam Baszkin , Chang-chun Ling

DOI: 10.1002/POC.610050814

关键词: CyclodextrinMonolayerSurface tensionMicelleOrganic chemistryAqueous solutionChemistrySolubilityDynamic light scatteringPolymer chemistryAmphiphile

摘要: The formation of micelles, vesicles and monomolecular layers by amphiphilic cyclodextrins possessing hydrophobic ester groups on the secondary hydroxyl face is described. physico-chemical properties these self-organizing systems were studied dynamic light scattering, variable-temperature 1H NMR, use lanthanide shift reagents, deposition Langmuir layers, solubility measurements aqueous non-aqueous surface tension activity measurements. results are interpreted in terms cylindrical geometry compounds which, coupled with presence a large planar polar head group, lead to self-organized both organic solvents also at air–water interface.

参考文章(12)
George A. Jeffrey, Hanna Maluszynska, The crystal structure and thermotropic liquid-crystal properties of N-n-undecyl-d-gluconamide Carbohydrate Research. ,vol. 207, pp. 211- 219 ,(1990) , 10.1016/0008-6215(90)84049-Z
Ping Zhang, Ling Chang-Chun, Anthony W. Coleman, Hélène Parrot-Lopez, Hervé Galons, Formation of amphiphilic cyclodextrins via hydrophobic esterification at the secondary hydroxyl face Tetrahedron Letters. ,vol. 32, pp. 2769- 2770 ,(1991) , 10.1016/0040-4039(91)85081-F
P. Charpin, I. Nicolis, F. Villain, C. de Rango, A. W. Coleman, β-Cyclodextrin–potassium hydroxide–water (1/1/8) Acta Crystallographica Section C Crystal Structure Communications. ,vol. 47, pp. 1829- 1833 ,(1991) , 10.1107/S0108270191002792
Volker Schurig, Hans-Peter Nowotny, Gas Chromatographic Separation of Enantiomers on Cyclodextrin Derivatives Angewandte Chemie. ,vol. 29, pp. 939- 957 ,(1990) , 10.1002/ANIE.199009393
Svetla Taneva, Katsuhiko Ariga, Yoshio Okahata, Waichiro Tagaki, Association between amphiphilic cyclodextrins and cholesterol in mixed insoluble monolayers at the air-water interface. Langmuir. ,vol. 5, pp. 111- 113 ,(1989) , 10.1021/LA00085A020
Kozo Shinoda, Tokio Yamaguchi, Ryohei Hori, The Surface Tension and the Critical Micelle Concentration in Aqueous Solution of β-D-Alkyl Glucosides and their Mixtures Bulletin of the Chemical Society of Japan. ,vol. 34, pp. 237- 241 ,(1961) , 10.1246/BCSJ.34.237
William N. Lipscomb, Molecular structure and function International Journal of Quantum Chemistry. ,vol. 40, pp. 1- 8 ,(1991) , 10.1002/QUA.560400706
A. Lattes, A. Meliani, E. Perez, I. Rico, FIRST EXAMPLE OF LIPOSOMES IN A SOLVENT OTHER THAN WATER New Journal of Chemistry. ,vol. 15, pp. 871- 872 ,(1991)