作者: Peter A. Sloan
DOI: 10.1016/B978-0-08-096355-6.00005-2
关键词: Atomic physics 、 Surface states 、 Intramolecular force 、 Chemical physics 、 Tunnel current 、 Desorption 、 Electron 、 Energy transfer 、 Dissociation (chemistry) 、 Chemistry 、 Quantum tunnelling
摘要: This chapter reviews the fundamental processes of STM molecular manipulation, desorption and intramolecular bond dissociation, produced by inelastic electron tunnelling. It is explained that interplay between dissociation reaction pathways can be tuned suitable adjustment tunnel conditions. Furthermore, it shown non local reactions involving transfer energy or charges across surface states also produce at distance.