Chronoamperometry of polymer-modified electrodes

作者: William T. Yap , Richard A. Durst , Elmo A. Blubaugh , Dwight D. Blubaugh

DOI: 10.1016/S0022-0728(83)80144-2

关键词: PolymerPolymer modifiedConstant (mathematics)Analytical chemistryDiffusionElectric fieldElectrodeChronoamperometryComposite materialChemistry

摘要: Abstract A theoretical analysis of charge-transport phenomena due to both diffusion and electrostatic migration in a polymer-modified electrode is presented for chronoamperometry. Concentration distributions current-time curves were derived the simple case constant electric field polymer film.

参考文章(8)
Pamela J. Peerce, Allen J. Bard, Polymer films on electrodes: Part II. Film structure and mechanism of electron transfer with electrodeposited poly(vinylferrocene) Journal of Electroanalytical Chemistry. ,vol. 112, pp. 97- 115 ,(1980) , 10.1016/S0022-0728(80)80011-8
Max Mason, Warren Weaver, The Settling of Small Particles in a Fluid Physical Review. ,vol. 23, pp. 412- 426 ,(1924) , 10.1103/PHYSREV.23.412
A.F. Diaz, T.C. Clarke, Reversible electrochemical oxidation of (CH)x films Journal of Electroanalytical Chemistry. ,vol. 111, pp. 115- 117 ,(1980) , 10.1016/S0022-0728(80)80082-9
E. Laviron, A multilayer model for the study of space distributed redox modified electrodes Journal of Electroanalytical Chemistry. ,vol. 112, pp. 1- 9 ,(1980) , 10.1016/S0022-0728(80)80002-7
P. Daum, J. R. Lenhard, D. Rolison, Royce W. Murray, Diffusional charge transport through ultrathin films of radiofrequency plasma polymerized vinylferrocene at low temperature Journal of the American Chemical Society. ,vol. 102, pp. 4649- 4653 ,(1980) , 10.1021/JA00534A014