(NMCp)2TiCl2-catalyzed reduction of aliphatic, aromatic and α,β-unsaturated ketones by Grignard reagent
作者： Yongmin Zhang , Zuyao Hu
DOI: 10.1016/S0040-4039(00)80430-X
关键词: Catalysis 、 Titanium 、 Ketone 、 Enone 、 Aliphatic compound 、 Metallocene 、 Grignard reagent 、 Chemistry 、 Bromide 、 Organic chemistry
摘要: Abstract Aliphatic, aromatic and α,β-unsaturated ketones were readily reduced to the corresponding secondary alcohols by iso-propylmagnesium bromide in presence of a catalytic amount bis(neomenthylcyclopentadienyl)titanium dichloride. A possible mechanism is discussed.
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