Preparation of high thermal stability MCM-41 in the low surfactant/silicon molar ratio synthesis systems

作者: Jian Yu , Jian-Lin Shi , Lian-Zhou Wang , Mei-Lin Ruan , Dong-Sheng Yan

DOI: 10.1016/S0167-577X(00)00289-5

关键词: Pulmonary surfactantSiliconMineralogyMesoporous materialChemical engineeringBET theoryThermal treatmentThermal stabilityMCM-41Materials scienceMolecular sieve

摘要: The preparation of a mesoporous molecular sieve MCM-41 both with bimodal framework and textural mesopores high thermal stability that results from thicker wall has been achieved by decreasing surfactant/silicon ratio synthesis gel. resultant material retains porosity large BET surface area even after treatment at 1273 K for 1 h in air.

参考文章(22)
Takashi Tatsumi, Keiko A. Koyano, Yoshinori Tanaka, Shinichi Nakata, Mechanical Stability of Mesoporous Materials, MCM-48 and MCM-41 Journal of Porous Materials. ,vol. 6, pp. 13- 17 ,(1999) , 10.1023/A:1009682915127
Cong-Yan Chen, Si-Qun Xiao, Mark E. Davis, Studies on ordered mesoporous materials III. Comparison of MCM-41 to mesoporous materials derived from kanemite Microporous Materials. ,vol. 4, pp. 1- 20 ,(1995) , 10.1016/0927-6513(94)00077-9
S. A. Bagshaw, E. Prouzet, T. J. Pinnavaia, Templating of Mesoporous Molecular Sieves by Nonionic Polyethylene Oxide Surfactants Science. ,vol. 269, pp. 1242- 1244 ,(1995) , 10.1126/SCIENCE.269.5228.1242
Karin Moller, Thomas Bein, Inclusion Chemistry in Periodic Mesoporous Hosts Chemistry of Materials. ,vol. 10, pp. 2950- 2963 ,(1998) , 10.1021/CM980243E
Eric Prouzet, Frederic Cot, Georges Nabias, André Larbot, Patricia Kooyman, Thomas J. Pinnavaia, Assembly of Mesoporous Silica Molecular Sieves Based on Nonionic Ethoxylated Sorbitan Esters as Structure Directors Chemistry of Materials. ,vol. 11, pp. 1498- 1503 ,(1999) , 10.1021/CM9810281
J. C. Vartuli, K. D. Schmitt, C. T. Kresge, W. J. Roth, M. E. Leonowicz, S. B. McCullen, S. D. Hellring, J. S. Beck, J. L. Schlenker, Effect of Surfactant/Silica Molar Ratios on the Formation of Mesoporous Molecular Sieves: Inorganic Mimicry of Surfactant Liquid-Crystal Phases and Mechanistic Implications Chemistry of Materials. ,vol. 6, pp. 2317- 2326 ,(1994) , 10.1021/CM00048A018
Robert Mokaya, William Jones, Efficient post-synthesis alumination of MCM-41 using aluminium chlorohydrate containing Al polycations Journal of Materials Chemistry. ,vol. 9, pp. 555- 561 ,(1999) , 10.1039/A807312K
Avelino Corma, Qiubin Kan, María T. Navarro, Joaquín Pérez-Pariente, Fernando Rey, Synthesis of MCM-41 with Different Pore Diameters without Addition of Auxiliary Organics Chemistry of Materials. ,vol. 9, pp. 2123- 2126 ,(1997) , 10.1021/CM970203V
K. A. Koyano, T. Tatsumi, Y. Tanaka, S. Nakata, Stabilization of Mesoporous Molecular-Sieves by Trimethylsilylation Journal of Physical Chemistry B. ,vol. 101, pp. 9436- 9440 ,(1997) , 10.1021/JP9724941
Ji Man Kim, Ja Hun Kwak, Shinae Jun, Ryong Ryoo, ION EXCHANGE AND THERMAL STABILITY OF MCM-41 The Journal of Physical Chemistry. ,vol. 99, pp. 16742- 16747 ,(1995) , 10.1021/J100045A039