Anatase TiO2 with Dominant High-Energy {001} Facets: Synthesis, Properties, and Applications

作者: Shengwei Liu , Jiaguo Yu , Mietek Jaroniec

DOI: 10.1021/CM200597M

关键词: FluorideScience, technology and societyNanotechnologyCatalysisEnergy transformationPhotocatalysisChemical processAdsorptionMaterials scienceAnatase

摘要: Control of the surface structure inorganic materials, in particular titania (TiO2), by chemical processes under nonequilibrium conditions is growing interest from scientific and utilitarian viewpoints. Titania one most important materials because its unique surface, electronic, photocatalytic properties, which make this material applicable many areas science technology ranging adsorption, catalysis photocatalysis to biomedicine, environmental monitoring cleanup, energy conversion storage, etc. Here we review existing strategies for synthesis anatase TiO2 micro- nanosheets with exposed high-energy {001} facets assembly these into various hierarchical structures. The are stabilized specific capping agents (typically, fluoride), used control growth crystals. presence improves significantly pro...

参考文章(69)
Hua Gui Yang, Cheng Hua Sun, Shi Zhang Qiao, Jin Zou, Gang Liu, Sean Campbell Smith, Hui Ming Cheng, Gao Qing Lu, None, Anatase TiO(2) single crystals with a large percentage of reactive facets Nature. ,vol. 453, pp. 638- 641 ,(2008) , 10.1038/NATURE06964
Young-wook Jun, Jae-Hyun Lee, Jin-sil Choi, Jinwoo Cheon, None, Symmetry-controlled colloidal nanocrystals: nonhydrolytic chemical synthesis and shape determining parameters. Journal of Physical Chemistry B. ,vol. 109, pp. 14795- 14806 ,(2005) , 10.1021/JP052257V
Jianming Li, Yuxiang Yu, Qingwei Chen, Jingjian Li, Dongsheng Xu, Controllable Synthesis of TiO2 Single Crystals with Tunable Shapes Using Ammonium-Exchanged Titanate Nanowires as Precursors Crystal Growth & Design. ,vol. 10, pp. 2111- 2115 ,(2010) , 10.1021/CG9012087
Zhi-Yuan Jiang, Qin Kuang, Zhao-Xiong Xie, Lan-Sun Zheng, Syntheses and Properties of Micro/Nanostructured Crystallites with High-Energy Surfaces Advanced Functional Materials. ,vol. 20, pp. 3634- 3645 ,(2010) , 10.1002/ADFM.201001243
Zhaoke Zheng, Baibiao Huang, Xiaoyan Qin, Xiaoyang Zhang, Ying Dai, Minhua Jiang, Peng Wang, Myung-Hwan Whangbo, Highly Efficient Photocatalyst: TiO2 Microspheres Produced from TiO2 Nanosheets with a High Percentage of Reactive {001} Facets Chemistry: A European Journal. ,vol. 15, pp. 12576- 12579 ,(2009) , 10.1002/CHEM.200902438
Jianming Li, Dongsheng Xu, Tetragonal faceted-nanorods of anatase TiO2 single crystals with a large percentage of active {100} facets. Chemical Communications. ,vol. 46, pp. 2301- 2303 ,(2010) , 10.1039/B923755K
Gang Liu, Hua Gui Yang, Xuewen Wang, Lina Cheng, Jian Pan, Gao Qing (Max) Lu, Hui-Ming Cheng, Visible Light Responsive Nitrogen Doped Anatase TiO2 Sheets with Dominant {001} Facets Derived from TiN Journal of the American Chemical Society. ,vol. 131, pp. 12868- 12869 ,(2009) , 10.1021/JA903463Q
Teruhisa Ohno, Koji Sarukawa, Michio Matsumura, Crystal faces of rutile and anatase TiO2 particles and their roles in photocatalytic reactions New Journal of Chemistry. ,vol. 26, pp. 1167- 1170 ,(2002) , 10.1039/B202140D
Haimin Zhang, Yanhe Han, Xiaolu Liu, Porun Liu, Hua Yu, Shanqing Zhang, Xiangdong Yao, Huijun Zhao, Anatase TiO2 microspheres with exposed mirror-like plane {001} facets for high performance dye-sensitized solar cells (DSSCs) Chemical Communications. ,vol. 46, pp. 8395- 8397 ,(2010) , 10.1039/C0CC03196H