Metal‐Catalyzed Reductive Coupling Reactions of Organic Halides with Carbonyl‐Type Compounds

作者: Toni Moragas , Arkaitz Correa , Ruben Martin

DOI: 10.1002/CHEM.201402509

关键词: Computational chemistryChemistryMetalOrganic chemistryCoupling reactionCatalysisHalideC c couplingAryl

摘要: Metal-catalyzed reductive coupling reactions of aryl halides and (pseudo)halides with carbonyl-type compounds have undergone an impressive development within the last years. These methodologies shown to be a powerful alternate strategy, practicality aside, use stoichiometric, well-defined, and, in some cases, air-sensitive organometallic species. In this Minireview, recent findings field are summarized, particular emphasis on mechanistic interpretation results future aspects area expertise.

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