作者: Toni Moragas , Arkaitz Correa , Ruben Martin
关键词: Computational chemistry 、 Chemistry 、 Metal 、 Organic chemistry 、 Coupling reaction 、 Catalysis 、 Halide 、 C c coupling 、 Aryl
摘要: Metal-catalyzed reductive coupling reactions of aryl halides and (pseudo)halides with carbonyl-type compounds have undergone an impressive development within the last years. These methodologies shown to be a powerful alternate strategy, practicality aside, use stoichiometric, well-defined, and, in some cases, air-sensitive organometallic species. In this Minireview, recent findings field are summarized, particular emphasis on mechanistic interpretation results future aspects area expertise.