6.17 C–O Bond Formation: Acylation of meso Diols
作者： T. Furuta , T. Kawabata
DOI: 10.1016/B978-0-08-095167-6.00619-4
关键词: Carbene 、 Stereochemistry 、 Imidazole 、 Planar chirality 、 Acylation 、 Amidine 、 Organic chemistry 、 Molecule 、 Chemistry 、 Desymmetrization 、 Axial chirality
摘要: Acylative desymmetrization of meso diols has attracted significant attention since it is useful for preparing optically active functionalized molecules in a single manipulation. Herein, recent aspects organocatalytic asymmetric acylation are described. Chiral organocatalysts, including chiral phosphines, 4-dimethylaminopyradine (DMAP) derivatives, imidazole N -heterocyclic carbene tertiary amines, and amidine derivatives acylative diols, Typical examples enzymatic also included.
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