Synthesis of CaSO4: Dy, CaSO4: Eu3+ and CaSO4: Eu2+ phosphors

作者: N.B. Ingle , S.K. Omanwar , P.L. Muthal , S.M. Dhopte , V.K. Kondawar

DOI: 10.1016/J.RADMEAS.2008.03.005

关键词: DosimetryDysprosiumPhysical chemistryChemistryPhosphorNuclear chemistryThermoluminescencePhotoluminescenceImpurityLuminescenceEuropium

摘要: Abstract CaSO 4 : Dy is a well-known phosphor for radiation dosimetry using thermoluminescence. Eu , phosphors also find applications in radio-photoluminescence and PLLCD. Various syntheses of these are described optimum procedures suggested. Effects various preparation methods on luminescence characteristics discussed terms elimination unwanted impurities, grain size, etc.

参考文章(22)
S V Upadeo, T K Gundurao, S V Moharil, Mechanism of thermoluminescence in CaF2:Eu and CaSO4:Eu phosphors Journal of Physics: Condensed Matter. ,vol. 6, pp. 9459- 9468 ,(1994) , 10.1088/0953-8984/6/44/024
Xiong Gong, Lei Liu, Wenju Chen, Preparation and photoluminescence of nanocrystalline MSO[sub 4]:xTb[sup 3+] (M=Ca, Sr, and Ba; x=0.001–0.005) Journal of Applied Physics. ,vol. 88, pp. 4389- 4393 ,(2000) , 10.1063/1.1289053
A. Vecht, A. C. Newport, P. A. Bayley, W. A. Crossland, Narrow band 390 nm emitting phosphors for photoluminescent liquid crystal displays Journal of Applied Physics. ,vol. 84, pp. 3827- 3829 ,(1998) , 10.1063/1.368561
D. Lapraz, H. Prevost, A. Baumer, P. Iacconi, M. Benabdesselam, P. Blanc, Effect of Thermal Preannealing on Fluorescence, Thermostimulated Luminescence and Cathodoluminescence of CaSO4 Doped with Europium Physica Status Solidi (a). ,vol. 181, pp. 515- 527 ,(2000) , 10.1002/1521-396X(200010)181:2<515::AID-PSSA515>3.0.CO;2-X
D. Van Der Voort, G. Blasse, The luminescence of europium(III) and cerium(III) in calcium sulfate: Activators with an effective charge Journal of Solid State Chemistry. ,vol. 87, pp. 350- 359 ,(1990) , 10.1016/0022-4596(90)90037-X
A. Winnacker, R. M. Shelby, R. M. Macfarlane, Photon-gated hole burning: a new mechanism using two-step photoionization. Optics Letters. ,vol. 10, pp. 350- 352 ,(1985) , 10.1364/OL.10.000350
T. Yamashita, N. Nada, H. Onishi, S. Kitamura, Calcium sulfate activated by thulium or dysprosium for thermoluminescence dosimetry. Health Physics. ,vol. 21, pp. 295- 300 ,(1971) , 10.1097/00004032-197108000-00016
M D Morgan, T G Stoebe, Optical absorption and luminescent processes in thermoluminescent CaSO4:Dy Journal of Physics: Condensed Matter. ,vol. 1, pp. 5773- 5781 ,(1989) , 10.1088/0953-8984/1/33/022
K S V Nambi, V N Bapat, A K Ganguly, Thermoluminescence of CaSO 4 doped with rare earths Journal of Physics C: Solid State Physics. ,vol. 7, pp. 4403- 4415 ,(1974) , 10.1088/0022-3719/7/23/027