In-situ characterization of bulk carbon nanotube behavior in a sheet under tensile load

作者: Abhendra K. Singh , Gregory R. Cobb , Ryan A. Kemnitz

DOI: 10.1016/J.MTCOMM.2018.10.017

关键词: ModulusStiffnessScanning electron microscopeTension (physics)Composite materialTensile testingCarbon nanotubeUltimate tensile strengthPreferential alignmentMaterials scienceMaterials ChemistryGeneral Materials ScienceMechanics of Materials

摘要: Abstract The present study characterizes orientation changes of randomly oriented nanotubes in carbon nanotube (CNT) sheet under externally applied tensile load. loads were using a microtester placed inside scanning electron microscope (SEM) that allowed in-situ observations morphological the CNT as load increased. It was observed entangled CNTs align themselves along loading direction. aligned eventually form separate distinct bundles prior to catastrophic failure. alignment is permanent and irreversible. overall stiffness strength also increases with increasing alignment. Reloading fully tension exhibits very stiff behavior higher Young’s modulus proportional limit when compared virgin goes through an phase evaluated be 40 MPa, while pre-existing 95 MPa. Raman spectroscopy confirmed exhibited preferential direction after testing. fails closer grip region where constraints created by prevent full resulting weaker near comparison rest sheet.

参考文章(31)
H.E. Misak, S. Mall, Time-dependent electrical properties of carbon nanotube yarns Carbon. ,vol. 30, pp. 207- 213 ,(2015) , 10.1016/S1872-5805(15)60186-X
Timothy G. Scott, Gary Blackburn, Michael Ashley, Ilker S. Bayer, Anindya Ghosh, Alexandru S. Biris, Abhijit Biswas, Advances in Bionanomaterials for Bone Tissue Engineering Journal of Nanoscience and Nanotechnology. ,vol. 13, pp. 1- 22 ,(2013) , 10.1166/JNN.2013.6733
Savas Berber, Young-Kyun Kwon, David Tománek, Unusually High Thermal Conductivity of Carbon Nanotubes Physical Review Letters. ,vol. 84, pp. 4613- 4616 ,(2000) , 10.1103/PHYSREVLETT.84.4613
X. Q. Chen, T. Saito, H. Yamada, K. Matsushige, Aligning single-wall carbon nanotubes with an alternating-current electric field Applied Physics Letters. ,vol. 78, pp. 3714- 3716 ,(2001) , 10.1063/1.1377627
T. W. Ebbesen, H. J. Lezec, H. Hiura, J. W. Bennett, H. F. Ghaemi, T. Thio, Electrical conductivity of individual carbon nanotubes Nature. ,vol. 382, pp. 54- 56 ,(1996) , 10.1038/382054A0
Amal M.K. Esawi, Mahmoud M. Farag, Carbon nanotube reinforced composites: Potential and current challenges Materials & Design. ,vol. 28, pp. 2394- 2401 ,(2007) , 10.1016/J.MATDES.2006.09.022
H.E. Misak, V. Sabelkin, S. Mall, R. Asmatulu, P.E. Kladitis, Failure analysis of carbon nanotube wires Carbon. ,vol. 50, pp. 4871- 4879 ,(2012) , 10.1016/J.CARBON.2012.06.015
Shu Li, Jin Gyu Park, Zhiyong Liang, Theo Siegrist, Tao Liu, Mei Zhang, Qunfeng Cheng, Ben Wang, Chuck Zhang, In situ characterization of structural changes and the fraction of aligned carbon nanotube networks produced by stretching Carbon. ,vol. 50, pp. 3859- 3867 ,(2012) , 10.1016/J.CARBON.2012.04.029