Copper ferrite nanoparticles: an effective and recoverable nanomagnetic catalyst for the synthesis of N, N ′,N ″‐trisubstituted guanidines from the addition reaction of anilines to carbodiimide

作者: Fatemeh Germaninezhad , Rahman Hosseinzadeh , Mahmood Tajbakhsh , Ali Beitollahi

DOI: 10.1049/MNL.2019.0519

关键词: Scanning electron microscopeCopperAddition reactionCatalysisFourier transform infrared spectroscopyFerrite (magnet)Magnetic nanoparticlesMaterials sciencePowder diffractionNuclear chemistry

摘要: In this study, copper ferrite (CuFe 2 O 4 ) nanoparticles were successfully prepared and employed as an efficient catalyst for the synthesis of guanidine derivatives through addition anilines to N, N-dicyclohexylcarcodiimide under solvent-free conditions. This magnetically retrievable was well characterised by Fourier transform infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy field emission scanning microscope-energy dispersive techniques. The can be readily recovered from reaction mixture use external magnet reused several times without remarkable loss its catalytic activity.

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