Synthesis of Cu2(OH)3Cl as facile and effective Fenton catalysts for mineralizing aromatic contaminants: Combination of σ-Cu-ligand and self-redox property
作者： Yan Wu , Hao Wang , Zeng Zhang , Hongyou Yin
DOI: 10.1016/J.APCATA.2021.118055
关键词: Redox 、 Medicinal chemistry 、 Bisphenol A 、 Phenol 、 Aromaticity 、 Catalysis 、 Aniline 、 Electron transfer 、 Benzoic acid 、 Chemistry
摘要: Abstract Cu2(OH)3Cl was synthesized as catalysts for mineralizing aromatic organics via Fenton reactions. Both Cu+ and Cu2+ are present in γ-Cu2(OH)3Cl, α-Cu2(OH)3Cl CuOHCl. Among them, γ-Cu2(OH)3Cl with the highest percentage is most active. Under relatively mild conditions, 88.7 % phenol, more than 85 bisphenol A, benzoic acid, 2-chlorophenol salicylic acid around 79 aniline mineralized at their ambient pH. Compared to reference CuSO4, CuO Cu2O, shows better mineralization ability, HO production H2O2 utilization efficiency. can form σ-Cu-ligand complexes phenolic hydroxyls contaminants. Such readily attacked by H2O2, causing electron transfer from rings formation of . Moreover, self-redox property when induced initiating thus reducing into Cu+. These effects could accelerate regeneration improve
sci-hub.st 参考文章(66)
V. Scuderi, G. Amiard, S. Boninelli, S. Scalese, M. Miritello, P.M. Sberna, G. Impellizzeri, V. Privitera, Photocatalytic activity of CuO and Cu2O nanowires Materials Science in Semiconductor Processing. ,vol. 42, pp. 89- 93 ,(2016) , 10.1016/J.MSSP.2015.08.008
Xinyue Zhang, Yaobin Ding, Heqing Tang, Xiaoyan Han, Lihua Zhu, Nan Wang, Degradation of bisphenol A by hydrogen peroxide activated with CuFeO2 microparticles as a heterogeneous Fenton-like catalyst: Efficiency, stability and mechanism Chemical Engineering Journal. ,vol. 236, pp. 251- 262 ,(2014) , 10.1016/J.CEJ.2013.09.051
M. E. Fleet, The crystal structure of paratacamite, Cu2(OH)3Cl Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 31, pp. 183- 187 ,(1975) , 10.1107/S0567740875002324
Qiang Sun, Chaojian Qin, Raman OH stretching band of water as an internal standard to determine carbonate concentrations Chemical Geology. ,vol. 283, pp. 274- 278 ,(2011) , 10.1016/J.CHEMGEO.2011.01.025
Brian C Dunn, Catherine Guenneau, Steven A Hilton, Jorg Pahnke, Edward M Eyring, Jacek Dworzanski, Henk LC Meuzelaar, JZ Hu, Mark S Solum, Ronald J Pugmire, None, Production of Diethyl Carbonate from Ethanol and Carbon Monoxide over a Heterogeneous Catalyst Energy & Fuels. ,vol. 16, pp. 177- 181 ,(2002) , 10.1021/EF0101816
Zhen Zhang, Xinbin Ma, Jing Zhang, Fei He, Shengping Wang, Effect of crystal structure of copper species on the rate and selectivity in oxidative carbonylation of ethanol for diethyl carbonate synthesis Journal of Molecular Catalysis A-chemical. ,vol. 227, pp. 141- 146 ,(2005) , 10.1016/J.MOLCATA.2004.10.023
T. Ghodselahi, M.A. Vesaghi, A. Shafiekhani, A. Baghizadeh, M. Lameii, XPS study of the Cu@Cu2O core-shell nanoparticles Applied Surface Science. ,vol. 255, pp. 2730- 2734 ,(2008) , 10.1016/J.APSUSC.2008.08.110
S.C. Lee, S.-H. Park, S.M. Lee, J.B. Lee, H.J. Kim, Synthesis and H2 uptake of Cu2(OH)3Cl, Cu(OH)2 and CuO nanocrystal aggregate Catalysis Today. ,vol. 120, pp. 358- 362 ,(2007) , 10.1016/J.CATTOD.2006.09.009
Man Seok Han, Byung Gwon Lee, Byoung Sung Ahn, Hoon Sik Kim, Dong Ju Moon, Suk In Hong, The role of copper chloride hydroxides in the oxidative carbonylation of methanol for dimethyl carbonate synthesis Journal of Molecular Catalysis A-chemical. ,vol. 203, pp. 137- 143 ,(2003) , 10.1016/S1381-1169(03)00131-6
M. Herrero, P. Benito, F.M. Labajos, V. Rives, Stabilization of Co2+ in layered double hydroxides (LDHs) by microwave-assisted ageing Journal of Solid State Chemistry. ,vol. 180, pp. 873- 884 ,(2007) , 10.1016/J.JSSC.2006.12.011