Preparation and characterization of starch-based composite films reinforced by cellulose nanofibers.
作者： Mahyar Fazeli , Meysam Keley , Esmaeil Biazar
DOI: 10.1016/J.IJBIOMAC.2018.04.186
关键词: Scanning electron microscope 、 Cellulose 、 Composite number 、 Tensile testing 、 Biocomposite 、 Ultimate tensile strength 、 Nanofiber 、 Nanocomposite 、 Composite material 、 Materials science
摘要: The current study deals with the preparation and characterization of polysaccharide-based biocomposite films acquired by incorporation cellulose nanofiber within glycerol plasticized matrix formed starch. application starch-based is limited due to highly hydrophilic nature poor mechanical properties. These problems are solved forming a nanocomposite thermoplastic starch (TPS) as (CNF) reinforcement. CNF successfully prepared from short henequen fibers which consist almost 60% chemo-mechanical process. TPS/CNF composite polymer solution casting method, their characterizations obtained water vapor transmission rate (WVTR), atomic force microscopy (AFM), oxygen (OTR), X-ray diffraction, light transmittance tensile test. 0.4 wt% loaded TPS showed approximately maximum improvement in strength. Tensile strength elastic modulus increased up 80% 170% respectively. Above 0.5 wt% CNF, starts deteriorate. WVTR OTR results show barrier properties matrix. AFM analysis shows topography surface nanocomposite. morphology nanofibers studied using scanning electron (SEM) (TEM).
sci-hub.se 参考文章(61)
Teena Thomas, Bipinbal P. Kanoth, C.M. Nijas, P.A. Joy, Joseph M. Joseph, Narayanan Kuthirummal, Eby T. Thachil, Preparation and characterization of flexible ferromagnetic nanocomposites for microwave applications Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 200, pp. 40- 49 ,(2015) , 10.1016/J.MSEB.2015.04.014
T.E. Timell, Wood Hemicelluloses: Part I Advances in carbohydrate chemistry. ,vol. 19, pp. 247- 302 ,(1964) , 10.1016/S0096-5332(08)60284-2
A Valadez-Gonzalez, J.M Cervantes-Uc, R Olayo, P.J Herrera-Franco, Chemical modification of henequén fibers with an organosilane coupling agent Composites Part B: Engineering. ,vol. 30, pp. 321- 331 ,(1999) , 10.1016/S1359-8368(98)00055-9
Franciele Maria Pelissari, Paulo José do Amaral Sobral, Florencia Cecilia Menegalli, Isolation and characterization of cellulose nanofibers from banana peels web science. ,vol. 21, pp. 417- 432 ,(2014) , 10.1007/S10570-013-0138-6
Wen He, Xiaochuan Jiang, Fengwen Sun, Xinwu Xu, Extraction and Characterization of Cellulose Nanofibers from Phyllostachys nidularia Munro via a Combination of Acid Treatment and Ultrasonication BioResources. ,vol. 9, pp. 6876- 6887 ,(2014) , 10.15376/BIORES.9.4.6876-6887
Maiju Hietala, Aji P. Mathew, Kristiina Oksman, Bionanocomposites of thermoplastic starch and cellulose nanofibers manufactured using twin-screw extrusion European Polymer Journal. ,vol. 49, pp. 950- 956 ,(2013) , 10.1016/J.EURPOLYMJ.2012.10.016
A. Nojoomi, M.A. Faghihi-Sani, M. Khoshkalam, Shear-rate dependence modeling of gelcast slurries: Effects of dispersant content and solid loading Ceramics International. ,vol. 40, pp. 123- 128 ,(2014) , 10.1016/J.CERAMINT.2013.05.112
A.N. Nakagaito, H. Yano, Novel high-strength biocomposites based on microfibrillated cellulose having nano-order-unit web-like network structure Applied Physics A. ,vol. 80, pp. 155- 159 ,(2005) , 10.1007/S00339-003-2225-2
Mehdi Jonoobi, Reza Oladi, Yalda Davoudpour, Kristiina Oksman, Alain Dufresne, Yahya Hamzeh, Reza Davoodi, Different preparation methods and properties of nanostructured cellulose from various natural resources and residues: a review Cellulose. ,vol. 22, pp. 935- 969 ,(2015) , 10.1007/S10570-015-0551-0
A. Awal, M. Rana, M. Sain, Thermorheological and mechanical properties of cellulose reinforced PLA bio-composites Mechanics of Materials. ,vol. 80, pp. 87- 95 ,(2015) , 10.1016/J.MECHMAT.2014.09.009