Structure of interfaces from uniformity of the chemical potential

作者: B. Widom

DOI: 10.1007/BF01011768

关键词: Van der Waals radiusVan der Waals equationvan der Waals forceHard spheresQuantum mechanicsStructure (category theory)Physics

摘要: It is shown that a generalized chemical potential suggested by the potential-distribution theory uniform even in nonuniform fluid. Leng, Rowlinson, and Thompson had already observed its uniformity through liquid-vapor interface penetrable-sphere model, mean-field approximation. Following those authors, we exploit of to obtain unified transparent derivations results Ono Kondo van der Waals on interfaces lattice-gas model attracting hard spheres, respectively, both

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