Nanoarchitectonics of Lotus Seed Derived Nanoporous Carbon Materials for Supercapacitor Applications.

作者: Ram Lal Shrestha , Rashma Chaudhary , Timila Shrestha , Birendra Man Tamrakar , Rekha Goswami Shrestha

DOI: 10.3390/MA13235434

关键词: Chemical engineeringMicroporous materialPorosityNanoarchitectonicsActivated carbonMesoporous materialSupercapacitorEnergy storageMaterials scienceCapacitance

摘要: Of the available environmentally friendly energy storage devices, supercapacitors are most promising because of their high density, ultra-fast charging-discharging rate, outstanding cycle life, cost-effectiveness, and safety. In this work, nanoporous carbon materials were prepared by applying zinc chloride activation lotus seed powder from 600 °C to 1000 electrochemical (supercapacitance) resulting in aqueous electrolyte (1M H2SO4) reported. Lotus seed-derived activated display hierarchically porous structures comprised micropore mesopore architectures, exhibited excellent supercapacitance performances. The specific surface areas pore volumes found ranges 1103.0–1316.7 m2 g−1 0.741–0.887 cm3 g−1, respectively. capacitance optimum sample was ca. 317.5 F at 5 mV s−1 272.9 1 A accompanied retention 70.49% a potential sweep rate 500 s−1. electrode also showed good capability 52.1% upon increasing current density 50 with exceptional cyclic stability 99.2% after 10,000 cycles demonstrating prospects for agricultural waste stuffs, such as seed, production performance required supercapacitor applications.

参考文章(66)
Y. Gogotsi, P. Simon, True Performance Metrics in Electrochemical Energy Storage Science. ,vol. 334, pp. 917- 918 ,(2011) , 10.1126/SCIENCE.1213003
M Molina-Sabio, F Rodrı́guez-Reinoso, Role of chemical activation in the development of carbon porosity Colloids and Surfaces A: Physicochemical and Engineering Aspects. ,vol. 241, pp. 15- 25 ,(2004) , 10.1016/J.COLSURFA.2004.04.007
Yan Wang, Zhiqiang Shi, Yi Huang, Yanfeng Ma, Chengyang Wang, Mingming Chen, Yongsheng Chen, SUPERCAPACITOR DEVICES BASED ON GRAPHENE MATERIALS Journal of Physical Chemistry C. ,vol. 113, pp. 13103- 13103 ,(2009) , 10.1021/JP902214F
A. Gutiérrez-Pardo, J. Ramírez-Rico, R. Cabezas-Rodríguez, J. Martínez-Fernández, Effect of catalytic graphitization on the electrochemical behavior of wood derived carbons for use in supercapacitors Journal of Power Sources. ,vol. 278, pp. 18- 26 ,(2015) , 10.1016/J.JPOWSOUR.2014.12.030
Michal Kruk, Mietek Jaroniec, Gas adsorption characterization of ordered organic-inorganic nanocomposite materials Chemistry of Materials. ,vol. 13, pp. 3169- 3183 ,(2001) , 10.1021/CM0101069
Xueliang Li, Changlong Han, Xiangying Chen, Chengwu Shi, Preparation and performance of straw based activated carbon for supercapacitor in non-aqueous electrolytes Microporous and Mesoporous Materials. ,vol. 131, pp. 303- 309 ,(2010) , 10.1016/J.MICROMESO.2010.01.007
Elzbieta Frackowiak, Carbon materials for supercapacitor application Physical Chemistry Chemical Physics. ,vol. 9, pp. 1774- 1785 ,(2007) , 10.1039/B618139M
Guoping Wang, Lei Zhang, Jiujun Zhang, A review of electrode materials for electrochemical supercapacitors Chemical Society Reviews. ,vol. 41, pp. 797- 828 ,(2012) , 10.1039/C1CS15060J
Kaustubha Mohanty, Mousam Jha, B. C. Meikap, M. N. Biswas, Preparation and Characterization of Activated Carbons from Terminalia Arjuna Nut with Zinc Chloride Activation for the Removal of Phenol from Wastewater Industrial & Engineering Chemistry Research. ,vol. 44, pp. 4128- 4138 ,(2005) , 10.1021/IE050162+
Thierry Brousse, Daniel Bélanger, Kazumi Chiba, Minato Egashira, Frédéric Favier, Jeffrey Long, John R Miller, Masayuki Morita, Katsuhiko Naoi, Patrice Simon, Wataru Sugimoto, Materials for electrochemical capacitors Nature Materials. ,vol. 7, pp. 845- 854 ,(2008) , 10.1038/NMAT2297