Porphyrinic Ionic Liquid Dyes: Synthesis and Characterization.
作者： Kai Li , Hatem M. Titi , Paula Berton , Robin D. Rogers
关键词: Alkyl 、 Solubility 、 Singlet oxygen 、 Ionic liquid 、 Inorganic chemistry 、 Characterization (materials science) 、 Porphyrin 、 Nitrobenzene 、 Chemistry
摘要: Four porphyrinic ionic liquids and four higher melting salts (>100 °C) were synthesized as potential photosensitizers from highly symmetric porphyrins by introducing alkyl chains exchanging anions to tune their solubility singlet oxygen generation capability. Among the compounds was 5,10,15,20-tetra(4-dodecylpyridinum)porphyrin tetrakis-bis(trifluoromethylsulfonyl)-amide, a room-temperature liquid that could be crystallized solvate with nitrobenzene.
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