A mixed valent heterometallic Cu(II)/Na(I) coordination polymer with sodium-phenyl bonds.
作者： Amitabha Datta , Kuheli Das , Chiara Massera , Jack K. Clegg , Chittaranjan Sinha
DOI: 10.1039/C4DT00189C
关键词: Sodium 、 Copper 、 Inorganic chemistry 、 Coordination polymer 、 Polymer chemistry 、 Ligand 、 Chemistry 、 Crystal structure 、 Schiff base 、 Single crystal 、 Sodium perchlorate
摘要: A mixed valent heterometallic CuII/NaI coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)) with copper(II) acetate and sodium perchlorate. In addition to presence alcohol oxygen–sodium bonds, single crystal X-ray structure reveals that 1D stabilised formation phenyl–sodium η2-bonds, face-to-face π–π contacts Cu–π interactions.
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