Hydrogen adsorption and hydrogen evolution reaction on a polycrystalline Pt electrode studied by surface-enhanced infrared absorption spectroscopy

作者: Keiji Kunimatsu , Takahiro Senzaki , Gabor Samjeské , Minoru Tsushima , Masatoshi Osawa

DOI: 10.1016/J.ELECTACTA.2006.12.007

关键词: Infrared spectroscopySpectroscopyAdsorptionElectrocatalystHydrogenElectrochemistryAnalytical chemistryReaction intermediateTafel equationChemistry

摘要: … H and the kinetics of HER, from which we conclude that terminal H atom is the reaction intermediate in HER … to discuss below the role of H upd in HER in the context of aforementioned …

参考文章(56)
Jacek Lipkowski, Philip N. Ross, Adsorption of molecules at metal electrodes VCH Publishers. ,(1992)
K. Kunimatsu, M.G. Samant, H. Seki, In-situ FT-IR spectroscopic study of bisulfate and sulfate adsorption on platinum electrodes Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 258, pp. 163- 177 ,(1989) , 10.1016/0022-0728(89)85170-8
Lam Wing H. Leung, Andrzej Wieckowski, Michael J. Weaver, In situ infrared spectroscopy of well-defined single-crystal electrodes: adsorption and electrooxidation of carbon monoxide on platinum(111) The Journal of Physical Chemistry. ,vol. 92, pp. 6985- 6990 ,(1988) , 10.1021/J100335A029
H. Angerstein-Kozlowska, B.E. Conway, W.B.A. Sharp, The real condition of electrochemically oxidized platinum surfaces Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 43, pp. 9- 36 ,(1973) , 10.1016/S0022-0728(73)80307-9
S. Holloway, J.K. Nørskov, Changes in the vibrational frequencies of adsorbed molecules due to an applied electric field Journal of Electroanalytical Chemistry. ,vol. 161, pp. 193- 198 ,(1984) , 10.1016/S0022-0728(84)80261-2
M. Osawa, M. Kuramitsu, A. Hatta, W. Suëtaka, H. Seki, Electromagnetic effect in enhanced infrared absorption of adsorbed molecules on thin metal films Surface Science. ,vol. 175, ,(1986) , 10.1016/0039-6028(86)90001-4