Charcoal production from waste pequi seeds for heat and power generation.

作者: Mara Rúbia da Silva Miranda , Carlos Alberto Gurgel Veras , Grace Ferreira Ghesti

DOI: 10.1016/J.WASMAN.2019.12.025

关键词: CharcoalHeat of combustionRaw materialCarbonizationProducer gasRenewable energyEnvironmental scienceBiomassPulp and paper industryPyrolysis

摘要: Abstract Many specialized technologies are available to convert waste biomass into secondary products that have a higher value and more convenient process than the original feedstock. This study evaluated potential of pequi seeds produce high-quality charcoal for subsequent gasification low-tar producer gas heat engine applications. We focused on characterization seeds, derived charcoal, collected bio-oil from slow pyrolysis conversion Thermodynamic equilibrium calculations were conducted assess performance parent its charcoal. also investigated thermal degradation kinetics through non-isothermal thermogravimetric analysis. Finally, two-step energy-extraction analysis was performed carbonization further utilization in an integrated gas-engine cycle. Slow (2 °C min−1, 430 °C) produced up 40% high-grade with 60% fixed carbon, 43% bio-oil, 16% light gases. The overall energy extraction efficiency estimated as 61%, based heating wet seeds. investigation confirmed could be considered promising renewable source combined power generation Brazilian agro-food industry.

参考文章(47)
Roberta M. Santos, Aglaéverton O. Santos, Eliana Midori Sussuchi, Juciara S. Nascimento, Álvaro S. Lima, Lisiane S. Freitas, Pyrolysis of mangaba seed: Production and characterization of bio-oil Bioresource Technology. ,vol. 196, pp. 43- 48 ,(2015) , 10.1016/J.BIORTECH.2015.07.060
Gang Xue, Marzena Kwapinska, Witold Kwapinski, Krzysztof M. Czajka, James Kennedy, James J. Leahy, Impact of torrefaction on properties of Miscanthus × giganteus relevant to gasification Fuel. ,vol. 121, pp. 189- 197 ,(2014) , 10.1016/J.FUEL.2013.12.022
K.C. Geőcze, L.C.A. Barbosa, P.H. Fidêncio, F.O. Silvério, C.F. Lima, M.C.A. Barbosa, Fyaz M.D. Ismail, Essential oils from pequi fruits from the Brazilian Cerrado ecosystem Food Research International. ,vol. 54, pp. 1- 8 ,(2013) , 10.1016/J.FOODRES.2013.06.005
T. Bui, R. Loof, S.C. Bhattacharya, Multi-stage reactor for thermal gasification of wood Energy. ,vol. 19, pp. 397- 404 ,(1994) , 10.1016/0360-5442(94)90118-X
Alcidênio Soares Pessoa, Rossana Podestá, Jane Mara Block, Elton Franceschi, Cláudio Dariva, Marcelo Lanza, Extraction of pequi (Caryocar coriaceum) pulp oil using subcritical propane: Determination of process yield and fatty acid profile Journal of Supercritical Fluids. ,vol. 101, pp. 95- 103 ,(2015) , 10.1016/J.SUPFLU.2015.03.006
Maria Puig-Arnavat, Joan Carles Bruno, Alberto Coronas, Review and analysis of biomass gasification models Renewable & Sustainable Energy Reviews. ,vol. 14, pp. 2841- 2851 ,(2010) , 10.1016/J.RSER.2010.07.030
S. Czernik, A. V. Bridgwater, Overview of Applications of Biomass Fast Pyrolysis Oil Energy & Fuels. ,vol. 18, pp. 590- 598 ,(2004) , 10.1021/EF034067U
Cheng Heng Pang, Sanyasi Gaddipatti, Gregory Tucker, Edward Lester, Tao Wu, Relationship between thermal behaviour of lignocellulosic components and properties of biomass. Bioresource Technology. ,vol. 172, pp. 312- 320 ,(2014) , 10.1016/J.BIORTECH.2014.09.042
Sergey Vyazovkin, Alan K. Burnham, José M. Criado, Luis A. Pérez-Maqueda, Crisan Popescu, Nicolas Sbirrazzuoli, ICTAC Kinetics Committee recommendations for performing kinetic computations on thermal analysis data Thermochimica Acta. ,vol. 520, pp. 1- 19 ,(2011) , 10.1016/J.TCA.2011.03.034
Michael Jerry Antal,, Eric Croiset, Xiangfeng Dai, Carlos DeAlmeida, William Shu-Lai Mok, Niclas Norberg, Jean-Robert Richard, Mamoun Al Majthoub, High-Yield Biomass Charcoal† Energy & Fuels. ,vol. 10, pp. 652- 658 ,(1996) , 10.1021/EF9501859