Detection of Environmental Contaminants by Biosensors
作者： Ajit Sadana
DOI: 10.1016/B978-044452784-4/50009-5
关键词: Kinetics 、 Fractal dimension 、 Analytical chemistry 、 Biosensor 、 Fractal analysis 、 Toluene 、 Chemistry 、 Xylene 、 Nonane 、 Dissociation (chemistry)
摘要: This chapter presents a fractal analysis for the binding and dissociation of various environmental pollutants either in solution or gas phase to receptors immobilized on different biosensor surfaces. The is offered as an alternative way improve understanding kinetics heterogeneous case with diffusion-limited reactions occurring structured Binding rate coefficients well dimensions are provided, basis prefactor aggregates, quantitative predictive equations developed coefficient k function dimension D f toluene concentration MC1061-pXylRS-lacZ; 3-methylbenzylchloride, 3-nitrotoluene, nonane MC1061-pXylRS-lacZ biosensor; molecular weight aromatic non-aromatic compounds solution; xylene solution. demonstrates that only mildly sensitive degree heterogeneity present surface. order dependence found be −0.7958 concentrations electrochemical biosensor, it equal 0.6470 aromatics non-aromatics (3-methylbenzylchloride, nonane) biosensor.
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