Failures of "Meso-Phase" Hypothesis Near Vapor-Liquid Critical Point
作者： I. H. Umirzakov
DOI: 10.1007/S10765-019-2483-7
关键词: Speed of sound 、 Materials science 、 Compressibility 、 Isothermal process 、 Phase transition 、 Critical point (thermodynamics) 、 Isochoric process 、 Isobaric process 、 Heat capacity 、 Thermodynamics
摘要: It is shown that the “meso-phase” hypothesis of Woodcock L. V. fails to describe quantitatively and qualitatively isochoric isobaric heat capacities, speed sound, long wavelength limit structural factor, isothermal compressibility, density fluctuations, Joule–Thompson coefficient throttling argon in region. also VdW-EOS can excess Gibbs energy rigidity near-critical point.
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sci-hub.st 参考文章(24)
Dmitry Yu. Ivanov, Critical Behavior of Non-Ideal Systems ,(2008)
Stanley M. Walas, Phase equilibria in chemical engineering ,(1985)
R. Span, W. Wagner, Equations of State for Technical Applications. II. Results for Nonpolar Fluids International Journal of Thermophysics. ,vol. 24, pp. 111- 162 ,(2003) , 10.1023/A:1022310214958
Rodney J. Baxter, Exactly solved models in statistical mechanics ,(1982)
David Johnston, Thermodynamic Properties of the van der Waals Fluid arXiv: Soft Condensed Matter. ,(2014) , 10.1088/978-1-627-05532-1
Mikhail Alekseevich Anisimov, Critical phenomena in liquids and liquid crystals ,(1991)
C. F. Curtiss, J. O. Hirschfelder, R. B. Bird, Molecular theory of gases and liquids ,(1954)
Ch. Tegeler, Roland Span, Wolfgang Wagner, A New Equation of State for Argon Covering the Fluid Region for Temperatures From the Melting Line to 700 K at Pressures up to 1000 MPa Journal of Physical and Chemical Reference Data. ,vol. 28, pp. 779- 850 ,(1999) , 10.1063/1.556037
Thomas K. Sherwood, Robert E. Street, Robert C. Reid, The Properties of Gases and Liquids ,(1977)
Andrea Pelissetto, Ettore Vicari, Critical phenomena and renormalization-group theory Physics Reports. ,vol. 368, pp. 549- 727 ,(2002) , 10.1016/S0370-1573(02)00219-3