A compositional model based on SAFT-VR and Maxwell-Stefan equations for pervaporative separation of aroma compounds from aqueous solutions
作者： Marzieh Aghakarimiha , Ahmadreza Raisi , Gholamreza Pazuki
DOI: 10.1016/J.MOLLIQ.2017.11.165
关键词: Isoamyl acetate 、 Pervaporation 、 Thermodynamics 、 Equation of state 、 Diffusion 、 Mass transfer 、 Aroma 、 Sorption 、 Aqueous solution 、 Materials science 、 Physical and Theoretical Chemistry 、 Spectroscopy 、 Materials Chemistry 、 Atomic and Molecular Physics, and Optics 、 Electronic, Optical and Magnetic Materials 、 Condensed matter physics
摘要: Abstract In this study, the SAFT-VR equation of state combined with Maxwell-Stefan theory was employed to develop a mass transfer model for pervaporation process. For purpose, used thermodynamic modeling sorption step as one main steps in process and applied describe transport permeating compounds through membrane. The diffusion coefficients were estimated based on free volume theory. then validated using experimental data obtained from pervaporative separation volatile aroma like 3-methyl butanal, isoamyl acetate n-hexanol their binary aqueous solutions polydimethylsiloxane (PDMS) proposed successfully able predict influence feed concentration operating temperature water partial fluxes factors. predicted total showed good agreement measured at various concentrations temperatures. Therefore, equations satisfactorily described hydrophobic without need any adjustable parameters dependent experiments.
elsevier.com
sci-hub.se 参考文章(45)
Carl L. Yaws, Chemical properties handbook : physical, thermodynamic, environmental, transport, safety, and health related properties for organic and inorganic chemicals Published in <b>1999</b> in New York NY) by McGraw-Hill. ,(1999)
Walter G. Chapman, George Jackson, Keith E. Gubbins, Phase equilibria of associating fluids Molecular Physics. ,vol. 65, pp. 1057- 1079 ,(2006) , 10.1080/00268978800101601
The Statistical Associating Fluid Theory (SAFT) John Wiley & Sons, Ltd. pp. 221- 259 ,(2009) , 10.1002/9780470747537.CH8
Hiroshi Fujita, Diffusion in polymer-diluent systems Fortschritte Der Hochpolymeren-Forschung. ,vol. 3, pp. 1- 47 ,(1961) , 10.1007/BFB0050514
David J. Walsh, Paul Zoller, Standard Pressure Volume Temperature Data for Polymers ,(1995)
J.G. Wijmans, R.W. Baker, The solution-diffusion model: a review Journal of Membrane Science. ,vol. 107, pp. 1- 21 ,(1995) , 10.1016/0376-7388(95)00102-I
Thomas K. Sherwood, Robert E. Street, Robert C. Reid, The Properties of Gases and Liquids ,(1977)
Olivera Trifunović, Frank Lipnizki, Gun Trägårdh, The influence of process parameters on aroma recovery by hydrophobic pervaporation Desalination. ,vol. 189, pp. 1- 12 ,(2006) , 10.1016/J.DESAL.2005.03.096
F. Lipnizki, G. Trägårdh, MODELLING OF PERVAPORATION: MODELS TO ANALYZE AND PREDICT THE MASS TRANSPORT IN PERVAPORATION Separation and Purification Methods. ,vol. 30, pp. 49- 125 ,(2001) , 10.1081/SPM-100102985
Amirhossein Mafi, Ahmadreza Raisi, Abdolreza Aroujalian, Computational fluid dynamics modeling of mass transfer for aroma compounds recovery from aqueous solutions by hydrophobic pervaporation Journal of Food Engineering. ,vol. 119, pp. 46- 55 ,(2013) , 10.1016/J.JFOODENG.2013.04.031