New calorimeter for measurement of the enthalpy of mixing of liquids. The enthalpy of mixing of benzene with carbon tetrachloride and of n-hexane with cyclohexane
作者： Harry Watts , E. C. W. Clarke , D. N. Glew
DOI: 10.1139/V68-142
关键词: Standard enthalpy of reaction 、 Enthalpy 、 Chemistry 、 Enthalpy of mixing 、 Calorimeter constant 、 Enthalpy change of solution 、 Entropy of mixing 、 Inorganic chemistry 、 Standard enthalpy of formation 、 Cyclohexane 、 Analytical chemistry
摘要: A high-precision, mixing calorimeter is described for the direct measurement of enthalpy liquid under constant pressure conditions. Tests using benzene – carbon tetrachloride system at 25 °C show a reaction between mercury and which leads to systematically high values heat mixing. with n-hexane–cyclohexane give maximum Δmh = 222.14 + 0.21 J/mole 0.586 cyclohexane mole fraction.
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