Clathrate formation from octaazaphthalocyanines possessing bulky phenoxyl substituents: a new cubic crystal containing solvent-filled, nanoscale voids.

作者: Saad Makhseed , Fadi Ibrahim , Jacob Samuel , Madeleine Helliwell , John E. Warren

DOI: 10.1002/CHEM.200701980

关键词: SolventCubic crystal systemCrystallographyChemistryNanoporousPhotochemistryNucleophilic aromatic substitutionPorphyrazinePhthalocyanineProton NMRSteric effects

摘要: The synthesis of octaazaphthalocyanine (AzaPc) derivatives, with bulky phenoxyl substituents placed at eight peripheral positions and containing either H+, Ni2+ or Zn2+ ions …

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