Hydrothermal synthesis, crystal structure and properties of Ni(II)-4f complexes based on 1H-benzimidazole-5,6-dicarboxylic acid.
作者： Ya-Guang Sun , Gang Xiong , Mei-Yan Guo , Fu Ding , Shu-Ju Wang
DOI: 10.1039/C2DT30277B
关键词: Benzimidazole 、 Crystallography 、 Inorganic chemistry 、 Crystal structure 、 Hydrothermal synthesis 、 Lanthanide contraction 、 Single crystal 、 Metal-organic framework 、 Chemistry 、 Dicarboxylic acid 、 Lanthanide
摘要: Nine novel heterometallic coordination polymers [Ln2Ni(Hbidc)2(SO4)2(H2O)8]n (Ln = Pr (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho (7), Er (8), Yb (9), H3bidc 1H-benzimidazole-5,6-dicarboxylic acid) have been synthesized under hydrothermal conditions and characterized by elemental analysis, FT-IR, TG analysis single crystal X-ray diffraction. revealed that all complexes present almost identical three-dimensional (3D) structures with PtS-type topology. Complexes 1–7 are isomorphous, the structure variation of 8 9 is induced lanthanide contraction effect. In additional, luminescence properties 2, 3 5–7, magnetic 4 6–8 were investigated.
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