Synergistic Effect of Graphene on Antidripping and Fire Resistance of Intumescent Flame Retardant Poly(butylene succinate) Composites

作者: Xin Wang , Lei Song , Hongyu Yang , Hongdian Lu , Yuan Hu

DOI: 10.1021/IE102566Y

关键词: Fire retardantComposite materialPolybutylene succinateThermogravimetric analysisGrapheneLimiting oxygen indexIntumescentInfrared spectroscopyScanning electron microscopeMaterials science

摘要: Intumescent flame retardant poly(butylene succinate) (IFRPBS) composites with enhanced fire resistance were prepared using graphene as synergist. The morphology of fracture surfaces the was investigated by scanning electron microscopy (SEM). limiting oxygen index (LOI) values increased from 23.0 for pure PBS to 31.0 IFRPBS 20 wt % IFR loading. addition further improved LOI and exhibited excellent antidripping properties. UL-94 V0 materials obtained a formulation 18 2 graphene. MFI measurement indicated that presence significantly melt viscosity restrained dripping. thermal degradation gas products IFRPBS/graphene systems monitored thermogravimetric analysis (TGA), real time Fourier transform infrared spectrometry (RTFTIR), analysis-Fourier (TG-FTIR). X-ray photoelectron spectroscopy ...

参考文章(29)
M. Gao, W. Wu, Y. Yan, Thermal degradation and flame retardancy of epoxy resins containing intumescent flame retardant Journal of Thermal Analysis and Calorimetry. ,vol. 95, pp. 605- 608 ,(2009) , 10.1007/S10973-008-9766-8
Kun Wu, Yuan Hu, Lei Song, Hongdian Lu, Zhengzhou Wang, Flame Retardancy and Thermal Degradation of Intumescent Flame Retardant Starch-Based Biodegradable Composites Industrial & Engineering Chemistry Research. ,vol. 48, pp. 3150- 3157 ,(2009) , 10.1021/IE801230H
Amanda L. Higginbotham, Jay R. Lomeda, Alexander B. Morgan, James M. Tour, Graphite Oxide Flame-Retardant Polymer Nanocomposites ACS Applied Materials & Interfaces. ,vol. 1, pp. 2256- 2261 ,(2009) , 10.1021/AM900419M
Shengwu Zhu, Wenfang Shi, Thermal degradation of a new flame retardant phosphate methacrylate polymer Polymer Degradation and Stability. ,vol. 80, pp. 217- 222 ,(2003) , 10.1016/S0141-3910(02)00401-9
George Z. Papageorgiou, Dimitris N. Bikiaris, Crystallization and melting behavior of three biodegradable poly(alkylene succinates). A comparative study Polymer. ,vol. 46, pp. 12081- 12092 ,(2005) , 10.1016/J.POLYMER.2005.10.073
Shibin Nie, Lei Song, Yuqiang Guo, Kun Wu, Weiyi Xing, Hongdian Lu, Yuan Hu, Intumescent Flame Retardation of Starch Containing Polypropylene Semibiocomposites: Flame Retardancy and Thermal Degradation Industrial & Engineering Chemistry Research. ,vol. 48, pp. 10751- 10758 ,(2009) , 10.1021/IE9012198
S. Peeterbroeck, F. Laoutid, J.-M. Taulemesse, F. Monteverde, J.-M. Lopez-Cuesta, J. B. Nagy, M. Alexandre, P. Dubois, Mechanical Properties and Flame‐Retardant Behavior of Ethylene Vinyl Acetate/High‐Density Polyethylene Coated Carbon Nanotube Nanocomposites Advanced Functional Materials. ,vol. 17, pp. 2787- 2791 ,(2007) , 10.1002/ADFM.200600936
Xiang-Cheng Bian, Jian-Hua Tang, Zhong-Ming Li, Zhong-Yuan Lu, Ai Lu, Dependence of flame-retardant properties on density of expandable graphite filled rigid polyurethane foam Journal of Applied Polymer Science. ,vol. 104, pp. 3347- 3355 ,(2007) , 10.1002/APP.25933