Fluorescence Turn-On Chemosensor for Highly Selective and Sensitive Detection and Bioimaging of Al3+ in Living Cells Based on Ion-Induced Aggregation

作者: Shilang Gui , Yanyan Huang , Fang Hu , Yulong Jin , Guanxin Zhang

DOI: 10.1021/AC504153C

关键词: Aqueous solutionIonDetection limitBiocompatibilityAnalytical chemistryChemistryPhotochemistryMetal ions in aqueous solutionHeLaFluorescenceAcetic acid

摘要: Herein, a new fluorescence turn-on chemosensor 2-(4-(1, 2, 2-triphenylvinyl) phenoxy) acetic acid (TPE-COOH) specific for Al³⁺ was presented by combining the aggregation-induced-emission (AIE) effect of tertaphenylethylene and the complexation capability of carboxyl. The introduction of carboxylic group provides the probe with good water-solubility which is important for analyzing biological samples. The recognition toward Al³⁺ induced the molecular aggregation and activated the blue fluorescence of the TPE core. The high …

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