The power-law reaction rate coefficient for barrierless reactions
作者： Yin Cangtao , Jiulin Du
DOI: 10.1088/1742-5468/2014/07/P07012
关键词: Thermodynamics 、 Molecular dynamics 、 Chemical kinetics 、 Power law 、 Function (mathematics) 、 Reaction rate 、 Materials science
摘要: We study the power-law reaction rate coefficient for barrierless reactions, when reactions take place in systems with distributions, and derive a generalized formula Gorin model. show that, unlike those bimolecular unimolcular due to lack of barriers, does not have function, thus is very strongly dependent on ν-parameter. Four are taken as application examples calculate new coefficients, which larger fitting ν-parameters can be exactly agreement measurements experimental studies.
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