The synthesis of anthracyclinones-ii : The synthesis of 7,9-bisdeoxycarminomycinone and -daunomycinone
作者： Alison E. Ashcroft , David T. Davies , James K. Sutherland
DOI: 10.1016/S0040-4020(01)91517-0
关键词: Quinone 、 Annulation 、 Nitro compound 、 Aldol condensation 、 Organic chemistry 、 Chemistry 、 Addition reaction 、 Nitronate
摘要: Abstract 7,9-Bisdeoxycarminomycinone has been synthesised from 5-hydroxyquinizarin by two annelation routes involving nitronate addition to C-2 and aldol condensation at C-3. 4-Demethoxy-7,9-bisdeoxydaunomycinone efficiently similar methods.
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